Die Synthese von Komplexen der allgemeinen Formel [M(Ylid)2Cl2](M=Pd, Pt, Ylid= z.B. (Ph)3PCHCOCH3, (Ph)3AsCHCOC6H5, (CH3)2SCH‐CO‐C6H5 oder C5H5NCH‐CO‐C6H5) und [Hg2(Ylid)2Cl4] wird beschrieben.
Mittels pH‐ und konduktometrischer Titrationen sowie Mößbauerspektroskopie werden die sich in den Systemen FeCl3/Phenol, FeC13/Brenzcatechin, FeC13/2,B‐Dihydroxybenzaldehyd, FeC13/2,3‐Dihydroxybenzoesäure und FeCl3 /Salicylsäure bildenden Fe‐Komplexe untersucht.
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