Innovations in nanogenerator technology foster pervading self-power devices for human use, environmental surveillance, energy transfiguration, intelligent energy storage systems, and wireless networks. Energy harvesting from ubiquitous ambient mechanical, thermal, and solar energies by nanogenerators is the hotspot of the modern electronics research era. Ferroelectric materials, which show spontaneous polarization, are reversible when exposed to the external electric field, and are responsive to external stimuli of strain, heat, and light are promising for modeling nanogenerators. This review demonstrates ferroelectric material-based nanogenerators, practicing the discrete and coupled pyroelectric, piezoelectric, triboelectric, and ferroelectric photovoltaic effects. Their working mechanisms and way of optimizing their performances, exercising the conjunction of effects in a standalone device, and multi-effects coupled nanogenerators are greatly versatile and reliable and encourage resolution in the energy crisis. Additionally, the expectancy of productive lines of future ensuing and propitious application domains are listed.