A composite material of plasmonic nanoparticles embedded in the scaffold of nanoporous Silicon offers unmatched capabilities to use it as a SERS substrate. The marriage of these components presents an...

We present an experimental investigation into the third-order nonlinearity of conventional crystalline (c-Si) and porous (p-Si) silicon with Z-scan technique at 800-nm and 2.4- μ m wavelengths. The Gaussian decomposition method is applied to extract the nonlinear refractive index, n 2 , and the two-photon absorption (TPA) coefficient, β , from the experimental results. The nonlinear refractive index obtained for c-Si is 7 ± 2 × 10 − 6 cm 2 /GW and for p-Si is − 9 ± 3 × 10 − 5 cm 2 /GW. The TPA coefficient was found to be 2.9 ± 0.9 cm/GW and 1.0 ± 0.3 cm/GW for c-Si and p-Si, respectively. We show an enhancement of the nonlinear refraction and a suppression of TPA in p-Si in comparison to c-Si, and the enhancement gets stronger as the wavelength increases.

We investigated and optimised the performance of the all-optical reflective modulation of the Mid-Wave Infrared (MWIR) signal by means of the optically-pumped sub-wavelength-structured optical membranes made of silicon. The membranes were optically pumped by a 60-femtosecond, 800-nm laser, while another laser operating in the MWIR ranging between 4 and 6 μ m was used to probe the optical response and modulation. We were able to achieve the conditions providing the modulation depth of 80% using the pump fluence of 3.8 mJ/cm 2 . To get a better insight into the performance and the modulation mechanism, we developed an optical model based on a combination of the Wentzel–Kramers–Brillouin approximation, Drude and Maxwell–Garnett theories. The model allowed us to estimate the values of the dielectric function, carrier concentration and scattering rate of the optically-excited membrane in the MWIR range. Using the model, we optimised the performance and found the conditions at which the reflective modulation can be operated with the ultrafast response of 0.55 ps and modulation contrast of 30%.

Coupling between nanoplasmonics and semiconducting materials can enhance and complement the efficiency of almost all semiconductor technologies. It has been demonstrated that such composites enhance the light coupling to nanowires, increase photocurrent in detectors, enable sub‐gap detection, allow DNA detection, and produce large non‐linearity. Nevertheless, the tailored fabrication using the conventional methods to produce such composites remains a formidable challenge. This work attempts to resolve that deficiency by deploying the immersion‐plating method to spontaneously grown gold clusters inside nano‐porous silicon (np‐Si). This method allows the fabrication of thin films of np‐Si with embedded gold nanoparticles (Au) and creates nanoplasmonic–semiconductor composites, np‐Si/Au, with fractional volume between 0.02 and 0.13 of the metallic component. Optical scattering measurements reveal a distinctive, 200 nm broad, localized surface plasmon (LSP) resonance, centered around 700 nm. Linear and non‐linear properties, and their time evolution are investigated by optically pumping the LSP resonance and probing the optical response with short wavelength infra‐red (2.5 μm) light. The ultrafast time‐resolved study demonstrates unambiguously that the non‐linear response is not only directly related to the LSP excitation, but strongly enhanced with respect to bare np‐Si, while its strength can be tuned by varying the metallic component.

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