Changes in deep ocean ventilation are commonly invoked as the primary cause of lower glacial atmospheric CO2. The water mass structure of the glacial deep Atlantic Ocean and the mechanism by which it may have sequestered carbon remain elusive. Here we present neodymium isotope measurements from cores throughout the Atlantic that reveal glacial–interglacial changes in water mass distributions. These results demonstrate the sustained production of North Atlantic Deep Water under glacial conditions, indicating that southern-sourced waters were not as spatially extensive during the Last Glacial Maximum as previously believed. We demonstrate that the depleted glacial δ13C values in the deep Atlantic Ocean cannot be explained solely by water mass source changes. A greater amount of respired carbon, therefore, must have been stored in the abyssal Atlantic during the Last Glacial Maximum. We infer that this was achieved by a sluggish deep overturning cell, comprised of well-mixed northern- and southern-sourced waters.

The neodymium isotopic composition of authigenic phases of deepsea sediment cores can be interpreted as reflecting past changes in water-mass mixing proportions if end-member water-mass compositions are constrained through time. Here we present three new records spanning 2480 to 4360 m depth in the North Atlantic Ocean that show seawater Nd isotope values in the early to mid-Holocene that are more radiogenic than values from the abyssal northwest Atlantic. This finding indicates that that the end-member composition of North Atlantic Deep Water was more stable within its core than it was at abyssal depths. The spatial distribution of the unradiogenic neodymium isotope values observed in the North Atlantic suggests a bottom source, and therefore that they were unlikely to have been due to the production of intermediate-depth Labrador Sea Water. We infer that the unradiogenic authigenic Nd isotope values were most likely derived from a pulse of poorly chemically weathered detrital material that was deposited into the Labrador Sea following Laurentide ice sheet retreat in the early Holocene. This unradiogenic sediment released neodymium into the bottom waters, yielding an unradiogenic seawater signal that was advected southward at abyssal depths and attenuated as it vertically mixed upward in the water column to shallower depths. The southward dispersion of these unradiogenic seawater values traces deep-water advection. However, the exact values observed at the most abyssal sites cannot be interpreted as proportionate to the strength of deep-water production without improved constraints on end-member changes.

The Nd isotope composition of seawater has been used to reconstruct past changes in the contribution of different water masses to the deep ocean. In the absence of contrary information, the Nd isotope compositions of endmember water masses are usually assumed constant during the Quaternary. Here we show that the Nd isotope composition of North Atlantic Deep Water (NADW), a major component of the global overturning ocean circulation, was significantly more radiogenic than modern during the Last Glacial Maximum (LGM), and shifted towards modern values during the deglaciation. We propose that weathering contributions of unradiogenic Nd modulated by the North American Ice Sheet dominated the evolution of the NADW Nd isotope endmember. If water mass mixing dominated the distribution of deep glacial Atlantic Nd isotopes, our results would imply a larger fraction of NADW in the deep Atlantic during the LGM and deglaciation than reconstructed with a constant northern endmember.

Antarctic Intermediate Water is an essential limb of the Atlantic meridional overturning circulation that redistributes heat and nutrients within the Atlantic Ocean. Existing reconstructions have yielded conflicting results on the history of Antarctic Intermediate Water penetration into the Atlantic across the most recent glacial termination. In this study we present leachate, foraminiferal, and detrital neodymium isotope data from three intermediate‐depth cores collected from the southern Brazil margin in the South Atlantic covering the past 25 kyr. These results reveal that strong chemical leaching following decarbonation does not extract past seawater neodymium composition in this location. The new foraminiferal records reveal no changes in seawater Nd isotopes during abrupt Northern Hemisphere cold events at these sites. We therefore conclude that there is no evidence for greater incursion of Antarctic Intermediate Water into the South Atlantic during either the Younger Dryas or Heinrich Stadial 1. We do, however, observe more radiogenic Nd isotope values in the intermediate‐depth South Atlantic during the mid‐Holocene. This radiogenic excursion coincides with evidence for a southward shift in the Southern Hemisphere westerlies that may have resulted in a greater entrainment of radiogenic Pacific‐sourced water during intermediate water production in the Atlantic sector of the Southern Ocean. Our intermediate‐depth records show similar values to a deglacial foraminiferal Nd isotope record from the deep South Atlantic during the Younger Dryas but are clearly distinct during the Last Glacial Maximum and Heinrich Stadial 1, demonstrating that the South Atlantic remained chemically stratified during Heinrich Stadial 1.

Ice core records show that atmospheric CO2 concentrations and Antarctic temperature were lower during the ‘lukewarm interglacials’ from 800 to 430 ka than the subsequent five interglacials. These different interglacial ‘strengths’ have been hypothesised to be controlled by Antarctic overturning circulation. How these variations in Antarctic overturning relate to Northern Atlantic overturning circulation, a major driver of Northern Hemisphere climate, is uncertain. Here we present a high-resolution record of authigenic neodymium isotopes—a water mass tracer that is independent of biological processes—and use it to reconstruct Atlantic overturning circulation during the last 800 kyr. This record reveals a similar proportion of North Atlantic Deep Water during the ‘lukewarm interglacials’ and the more recent interglacials. This observation suggests that the provenance of deep water in the Atlantic Ocean can be decoupled from ventilation state of the Southern Ocean and consequently the atmospheric concentration of carbon dioxide.