[1] The 2010 Eyjafjallajökull eruption in Iceland produced mildly alkaline basalt that was emitted during the initial flank eruptive phase, whereas tephra predominately of benmorite composition was erupted during the second explosive phase from the summit of the volcano. These latter magmas show pervasive magma mingling between basalts and silicic magma. Glass and coexisting equilibrium mineral analyses have been used to define pressure-temperature crystallization paths for the eruption based on melt, clinopyroxene-melt and plagioclase-melt thermobarometry. Temperature calculations show that the early basaltic eruptions from the flank eruption have magmatic temperatures of around 1170 C (AE25 C) and a narrow temperature range (<30 C) at any given depth. In contrast, benmoritic products crystallized at lower temperatures (1000-1060 C). Pressure estimates yield an average pressure of 5.6-6.4 kbar (AE1.5 kbar) for the basaltic tephra and variable but lower pressures for the benmoritic samples ranging down to 0.6 kbar. The mafic magma mainly crystallized in the deeper crust (16-18 km), whereas mingled magma from the summit eruption crystallized at more shallow crustal levels (2-5 km) suggesting multistage magma ascent. Magmatic water concentrations were estimated with plagioclase-melt hygrometry. The maximum average water content of 1.8 wt % H 2 O, obtained in one of the summit samples, is in agreement with melt inclusion observations. Water concentration of this or lower levels is demonstrated to only have limited effect on the pressure-temperature calculations.
Abstract. Injection of basaltic magmas into silicic crustal holding chambers and subsequent magma mingling or mixing is a process that has been recognised since the late seventies as resulting in explosive eruptions. Detailed reconstruction and assessment of the mixing process caused by such intrusion is now possible because of the exceptional time-sequence sample suite available from the tephra fallout of the 2010 summit eruption at Eyjafjallajökull volcano in South Iceland. Fallout from 14 to 19 April contains three glass types of basaltic, intermediate, and silicic compositions recording rapid magma mingling without homogenisation, involving evolved FeTi-basalt and silicic melt with composition identical to that produced by the 1821-1823 AD Eyjafjallajökull summit eruption. The time-dependent change in the magma composition suggests a binary mixing process with changing end-member compositions and proportions. Beginning of May, a new injection of primitive basalt was recorded by deep seismicity, appearance of Mgrich olivine phenocrysts together with high sulphur dioxide output and presence of sulphide crystals. Thus, the composition of the basaltic injection became more magnesian and hotter with time provoking changes in the silicic mixing end-member from pre-existing melt to the solid carapace of the magma chamber. Finally, decreasing proportions of the mafic end-member with time in the erupted mixedmagma demonstrate that injections of Mg-rich basalt was the motor of the 2010 Eyjafjallajökull explosive eruption, andCorrespondence to: O. Sigmarsson (olgeir@raunvis.hi.is) that its decreasing inflow terminated the eruption. Significant quantity of silicic magma is thus still present in the interior of the volcano. Our results show that detailed sampling during the entire eruption was essential for deciphering the complex magmatic processes at play, i.e. the dynamics of the magma mingling and mixing. Finally, the rapid compositional changes in the eruptive products suggest that magma mingling occurs on a timescale of a few hours to days whereas the interval between the first detected magma injection and eruption was several months.
In recent years, increasing attention has been given to the potential supply risks of critical battery materials, such as cobalt, for electric mobility transitions. While battery technology and recycling advancement are two widely acknowledged strategies for addressing such supply risks, the extent to which they will relieve global and regional cobalt demand–supply imbalance remains poorly understood. Here, we address this gap by simulating historical (1998-2019) and future (2020-2050) global cobalt cycles covering both traditional and emerging end uses with regional resolution (China, the U.S., Japan, the EU, and the rest of the world). We show that cobalt-free batteries and recycling progress can indeed significantly alleviate long-term cobalt supply risks. However, the cobalt supply shortage appears inevitable in the short- to medium-term (during 2028-2033), even under the most technologically optimistic scenario. Our results reveal varying cobalt supply security levels by region and indicate the urgency of boosting primary cobalt supply to ensure global e-mobility ambitions.
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