Polymer and textiles have a vast number of advantages and attractiveness as a material. However, despite these advantageous, polymers have limitations. In general, special surface properties with regard to chemical composition, hydrophilicity, roughness, crystallinity, conductivity, lubricity, and cross-linking density are required for successful application of polymers in such wide fields as adhesion, membrane filtration, coatings, friction and wear, composites, microelectronic devices, thin-film technology and biomaterials, and so on. Unfortunately, polymers very often do not possess the surface properties needed for these applications. In fact, polymeric fibers that are mechanically strong, chemically stable, and easy to process usually will have inert surfaces both chemically and biologically. Vice versa, those polymers having active surfaces usually do not possess excellent mechanical properties which are critical for their successful application. Due to this dilemma, surface modification of the polymeric fibers without changing the bulk properties has been a classical research topic for many years, and is still extensive studies as new applications of polymeric materials emerge, especially in the fields of biotechnology, bioengineering, and most recently in nanotechnology. Modification is used to designate a deliberate change in composition or structure leading to an improvement in different type of fiber properties. The challenge is, however, that there does not exist an ideal modification that eliminates all the negative properties and preserves all the positive properties of the fibers. This is why there are a great number of different single-purpose modifications. [1]