As more electronics are used in down-hole energy exploration, under the hood automotive applications, and in other environments where temperatures exceed 200 °C; there is a need for compact passive magnetic components that operate reliably at elevated temperatures. Most ferrites used to make multi layer ceramic inductors have Curie temperatures in the 100–200 °C range. As temperatures rise above the Curie point ferrites lose their magnetic properties and become paramagnetic. This means that traditional multi-layer ceramic inductors suffer severe performance degradation when operated at elevated temperatures. Therefore, ferrite materials with higher Curie temperatures need to be developed to increase device performance and reliability at these high temperatures. In this work inductors were made from a low-temperature, co-fire compatible, ferrite with a Curie temperature of 350 °C. The inductors were first subjected to a 1000 hour life test at 300 °C during which the electrical parameters were found to change no more than 4 %. The inductance, resistance, core loss, and saturation flux density of the inductors were measured at various temperatures. Additional testing focused on the effect of temperature on the device's frequency profile and performance changes under thermal cycling and thermal shock.
While ferrite Low Temperature Co-fired Ceramic (LTCC) inductor and transformer developments have undergone thermal shock and high temperature aging that focused on the stability of their electrical characteristics (resistance, inductance), little attention has been paid to their termination reliability at high temperatures. Testing has been done on AgPt and AgPd terminations with Ag5Cd95 and Pb88Sn10Ag2 solders for 2000 and 25 hrs, respectively. However, Ag5Cd95 is unusable in commercial applications due to ROHS restrictions while Pb88Sn10Ag2 is undesirable because of the high lead content. Sn96 solder and wire bonding are common attachment methods that have not been vetted. Initial investigations show that high Sn solders may interfere with bonding between the AgPt and AgPd termination materials and the ferrite bulk of the part. An alternative terminal structure for using Sn96 solder is created by electroplating Au and Ni; however, electroplating to ferrite is challenging due to the masking involved. Also, the preferred materials for wire bonding are thick film, thin film or electroplated Au. To this end an alternative termination structure using Au sputter deposited onto sputter deposited Ti is being investigated. This structure was chosen for its potential to be a lower cost alternative to thick film Au and for its potential for simpler manufacturing than electroplating. Tests involved measuring bond strength and resistance after thermal ageing and thermal shock. Baseline solder joint pull tests show strength comparable to other termination methods. Some issues with solder wetting of the terminals have been noted.
Environments prone to vibration and shocks can cause premature failure in small wire-wound transformers due to cracked cores and broken wires. These problems are only exacerbated by temperatures exceeding 200 °C where the heat causes organic compounds to age rapidly. As more electronics are used in harsh, high temperature environments, high reliability, compact transformers for use in power, filtering, and isolation applications are needed. To address this need monolithic low-temperature co-fired ceramic transformers were developed. In this work transformers were made from a low-temperature, co-fire compatible, ferrite with a Curie temperature of 350 °C. The transformers were first subjected to a 2,000 hour life test at 250 °C in which the transformer was used to charge a load capacitor once every two seconds. The inductance, resistance, core loss, and saturation flux density of the transformers were measured at various temperatures. Additional testing focused on the effect of temperature on the device's frequency profile and performance changes under thermal cycling.
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