Silver nanoparticles utilizing the surface plasmon resonance effect of silver have been used to color merino wool fibers as well as imparting antimicrobial and antistatic properties to them to produce a novel silver nanoparticle-wool composite material. This is accomplished by the reduction of silver ions in solution by trisodium citrate (TSC) in the presence of merino wool fibers or fabrics. The silver metal nanoparticles simultaneously bind to the amino acids of the keratin protein in the wool fibers using TSC as the linker. The colors of the resulting merino wool-silver nanoparticle composites range from yellow/brown to red/brown and then to brown/black, because of the surface plasmon resonance effect of silver, and are tuned by controlling the reduction of silver ions to silver nanoparticles to give the required particle size on the fiber surface. In addition to the surface plasmon resonance optical effects, the silver nanoparticle-wool composites exhibit effective antimicrobial activity, thus inhibiting the growth of microbes and also an increase in the electrical conductivity, imparting antistatic properties to the fibers. Therefore, silver nanoparticles function as a simultaneous colorant and antimicrobial and antistatic agent for wool. Chemical and physical characterizations of the silver nanoparticle-merino wool composite materials have been carried out using scanning electron microscopy, transmission electron microscopy, energy-dispersive spectroscopy, synchrotron radiation X-ray diffraction, atomic absorption spectroscopy, X-ray photoelectron spectroscopy, direct-current electrical conductivity measurements, wash-fast and rub-fast tests, and antimicrobial tests.
Surface-alkoxylated silica can be prepared by reacting precipitated silica with high-boiling
and polymeric alcohols. The structure of the products was investigated through 13C and 29Si
MAS NMR experiments. The influence of the alkoxy group structure and density on the
hydrolytic stability of the alkoxylated silicas was determined through contact with boiling
water. Use of polymeric or branched alcohols increased the hydrolytic stability of surface-alkoxylated silicas compared to straight-chain alcohols. The rate of surface substitution is
increased by both acid and base catalysis.
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