We studied soils on high‐purity limestones of Quaternary age on the western Atlantic Ocean islands of Barbados, the Florida Keys, and the Bahamas. Potential soil parent materials in this region, external to the carbonate substrate, include volcanic ash from the island of St. Vincent (near Barbados), volcanic ash from the islands of Dominica and St. Lucia (somewhat farther from Barbados), the fine‐grained component of distal loess from the lower Mississippi River Valley, and wind‐transported dust from Africa. These four parent materials can be differentiated using trace elements (Sc, Cr, Th, and Zr) and rare earth elements that have minimal mobility in the soil‐forming environment. Barbados soils have compositions that indicate a complex derivation. Volcanic ash from the island of St. Vincent appears to have been the most important influence, but African dust is a significant contributor, and even Mississippi River valley loess may be a very minor contributor to Barbados soils. Soils on the Florida Keys and islands in the Bahamas appear to have developed mostly from African dust, but Mississippi River valley loess may be a significant contributor. Our results indicate that inputs of African dust are more important to the genesis of soils on islands in the western Atlantic Ocean than previously supposed. We hypothesize that African dust may also be a major contributor to soils on other islands of the Caribbean and to soils in northern South America, central America, Mexico, and the southeastern United States. Dust inputs to subtropical and tropical soils in this region increase both nutrient‐holding capacity and nutrient status and thus may be critical in sustaining vegetation.
Loess is extensive in central Alaska, but there are uncertainties about its source and the direction of paleo winds that deposited it. Both northerly and southerly winds have been inferred. The most likely sources of loess are the Tanana River (south), the Nenana River (southeast), and the Yukon River (north). Late Quaternary loess in central Alaska has immobile trace-element compositions (Cr/Sc, Th/Ta, Th/Sc, Th/U, Eu/Eu*, GdN/YbN) that indicate derivation mostly from the Tanana River. However, other ratios (As/Sb, Zr/Hf, LaN/YbN) and quantitative modeling indicate that the Yukon River was also a source. During the last glacial period, there may have been a longer residence time of the Siberian and Canadian high-pressure cells, along with a strengthened Aleutian low-pressure cell. This would have generated regional-scale northeasterly winds and explains derivation of loess from the Yukon River. However, superimposed upon this synoptic-scale circulation, there may have been strong, southerly katabatic winds from expanded glaciers on the northern flank of the Alaska Range. These winds could have provided eolian silt from the Tanana River. Yukon River and Tanana River sediments are highly calcareous, whereas Fairbanks-area loess is not. This suggests that carbonate leaching in loess kept ahead of sedimentation and that late Quaternary loess in central Alaska was deposited relatively slowly.
[1] Islands are natural dust traps, and San Clemente Island, California, is a good example. Soils on marine terraces cut into Miocene andesite on this island are clay-rich Vertisols or Alfisols with vertic properties. These soils are overlain by silt-rich mantles, 5-20 cm thick, that contrast sharply with the underlying clay-rich subsoils. The silt mantles have a mineralogy that is distinct from the island bedrock. Silt mantles are rich in quartz, which is rare in the island andesite. The clay fraction of the silt mantles is dominated by mica, also absent from local andesite, and contrasts with the subsoils, dominated by smectite. Ternary plots of immobile trace elements (Sc-Th-La and Ta-Nd-Cr) show that the island andesite has a composition intermediate between average upper continental crust and average oceanic crust. In contrast, the silt and, to a lesser extent, clay fractions of the silt mantles have compositions closer to average upper continental crust. The silt mantles have particle size distributions similar to loess and Mojave Desert dust, but are coarser than long-range-transported Asian dust. We infer from these observations
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