No abstract

The three wavelength extinction method (3-WEM) was applied for the on-line particle analysis of suspensions of monodisperse latex beads and polydisperse metal oxide particles of industrial interest. Comparative measurements were performed by photon correlation spectroscopy (PCS). The data of latex particles obtained by 3-WEM and PCS are in good agreement with the manufacture’s values. Also, the values of oxide particles measured by means of the two techniques are in reasonable agreement despite of the irregular particle shape. Discrepancies are observed by comparing the oxide particle size results with those of scanning electron microscopy, which is due to the broad sample distributions and shape irregularities.

Soot particles emitted from a light duty (LD) Volkswagen diesel engine running at different operating points (speed and torque levels) are analyzed for mean size determination using a laser-based three Wavelength Extinction Method (3-WEM). For this reason, collected soot samples are suspended using an appropriate sample preparation technique with optimized conditions of sonication as it revealed its effect on the soot mean particle size measured by 3-WEM.An online Scanning Mobility Particle Analyzer (SMPS) is also used to measure soot emission at identical engine operating points. Size values obtained from SMPS are lower than those of suspended soot samples obtained from 3-WEM. The size discrepancies are mainly related to the required sample preparation procedure employed for 3-WEM measurements. The engine operating points affect, differently, the size measurements obtained from SMPS and 3-WEM.Sedimentation Field-Flow Fractionation (SdFFF) is used for density determination of soot samples based on size measurements of fractions collected at peak maxima Address correspondence to Philippe J. P. Cardot1525 of fractograms using the off-line hyphenation with 3-WEM. It is assumed that a size dependent separation of soot particles occurred with a uniform particle density over the whole size distribution. An average density value is used for the conversion of soot fractograms to size distributions. Discrepancies are also found with size distribution profiles obtained from SMPS for the same engine operating points, due to the sample preparation procedure employed for SdFFF measurements.