[1] We investigate the physics of laboratory earthquake precursors in a biaxial shear configuration. We conduct laboratory experiments at room temperature and humidity in which we shear layers of glass beads under applied normal loads of 2-8 MPa and with shearing rates of 5-10 μm/s. We show that above~3 MPa load, acoustic emission (AE), and shear microfailure (microslip) precursors exhibit an exponential increase in rate of occurrence, culminating in stick-slip failure. Precursors take place where the material is in a critical state-still modestly dilating, yet while the macroscopic frictional strength is no longer increasing.

Hysteresis is observed in sorption-induced swelling in various soft nanoporous polymers. The associated coupling mechanism responsible for the observed sorption-induced swelling and associated hysteresis needs to be unraveled. Here we report a microscopic scenario for the molecular mechanism responsible for hysteresis in sorption-induced swelling in natural polymers such as cellulose using atom-scale simulation; moisture content and swelling exhibit hysteresis upon ad- and desorption but not swelling versus moisture content. Different hydrogen bond networks are examined; cellulose swells to form water–cellulose bonds upon adsorption but these bonds do not break upon desorption at the same chemical potential. These findings, which are supported by mechanical testing and cellulose textural assessment upon sorption, shed light on experimental observations for wood and other related materials.

The standardised Glaser method for calculation, prediction and evaluation of moisture performance is considered as rarely applicable. The present state of knowledge, analytical as well as experimental, concerning heat, air and moisture demands updating of standards. This paper presents five numerical benchmark cases for the quality assessment of simulation models for one-dimensional heat, air and moisture (HAM) transfer. In one case, the analytical solution is known and excellent agreement between several solutions from different universities and institutes is obtained. In the remaining four cases, consensus solutions have been found, with good agreement between different HAM models. The work presented here is an outcome of the EU-initiated project for standardisation of HAM calculation methods (HAMSTAD WP2).

Biocides are included in organic building façade coatings as protection against biological attack by algae and fungi but have the potential to enter the environment via leaching into runoff from wind driven rain. The following field study correlates wind driven rain to runoff and measured the release of several commonly used organic biocides (terbutryn, Irgarol 1051, diuron, isoproturon, OIT, DCOIT) in organic façade coatings from four coating systems. During one year of exposure of a west oriented model house façade in the Zurich, Switzerland area, an average of 62.7 L/m(2), or 6.3% of annual precipitation came off the four façade panels installed as runoff. The ISO method for calculating wind driven rain loads is adapted to predict runoff and can be used in the calculation of emissions in the field. Biocide concentrations tend to be higher in the early lifetime of the coatings and then reach fairly consistent levels later, generally ranging on the order of mg/L or hundreds of μg/L. On the basis of the amount remaining in the film after exposure, the occurrence of transformation products, and the calculated amounts in the leachate, degradation plays a significant role in the overall mass balance.