Laser-induced fluorescence of a fuel tracer is a very sensitive technique to image in-cylinder liquid fuel films, but quantification of the measured film thickness has proven difficult so far. This article describes improvements in the quantification procedure and presents an example application in a motored, optically accessible spark-ignition engine with direct injection. We designed a calibration tool that could be pressurized and heated, allowing investigation of the laser-induced fluorescence intensities at temperatures exceeding the liquid's standard-pressure boiling point. The fluorescence intensity of liquid toluene and 3-Pentanone dissolved in isooctane upon excitation with a pulsed laser at 266 nm was investigated as a function of temperature and pressure. Consistent with the literature results on gas-phase laser-induced fluorescence, the signal from toluene was much stronger than from 3-Pentanone, about two orders of magnitude for films thinner than 50 mm. Laser-induced fluorescence from both tracers decreased with increasing temperature but that of toluene significantly more. The response to pressure was less pronounced. For imaging across a large field of view, the spatial non-uniformity of laser excitation and detection efficiency was taken into account using a solid fluorescing substrate, an inexpensive Schott-glass WG280 filter. Isooctane with 0.5 vol.% toluene was used for application in the motored engine, imaging the liquid film on the piston-top window after direct injection from a central multi-hole injector. Air as a bulk gas was found to be advantageous over nitrogen in that gas-phase fluorescence was quenched by oxygen. The imaged film distributions and thicknesses and the derived total fuel film mass were physically plausible. Consistent with the recent literature results from a constant pressure vessel, increasing injection pressure from 50 to 100 bar did not decrease wall wetting but further increase to 200 bar did.

Model guided application (MGA) combining physico-chemical internal combustion engine simulation with advanced analytics offers a robust framework to develop and test particle number (PN) emissions reduction strategies. The digital engineering workflow presented in this paper integrates the kinetics & SRM Engine Suite with parameter estimation techniques applicable to the simulation of particle formation and dynamics in gasoline direct injection (GDI) spark ignition (SI) engines. The evolution of the particle population characteristics at engine-out and through the sampling system is investigated. The particle population balance model is extended beyond soot to include sulphates and soluble organic fractions (SOF). This particle model is coupled with the gas phase chemistry precursors and is solved using a sectional method. The combustion chamber is divided into a wall zone and a bulk zone and the fuel impingement on the cylinder wall is simulated. The wall zone is responsible for resolving the distribution of equivalence ratios near the wall, a factor that is essential to account for the formation of soot in GDI SI engines. In this work, a stochastic reactor model (SRM) is calibrated to a single-cylinder test engine operated at 12 steady state load-speed operating points. First, the flame propagation model is calibrated using the experimental in-cylinder pressure profiles. Then, the population balance model parameters are calibrated based on the experimental data for particle size distributions from the same operating conditions. Good agreement was obtained for the incylinder pressure profiles and gas phase emissions such as NOx. The MGA also employs a reactor network approach to align with the particle sampling measurements procedure, and the influence of dilution ratios and temperature on the PN measurement is investigated. Lastly, the MGA and the measurements procedure are applied to size-resolved chemical characterisation of the emitted particles.

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Large Eddy Simulations (LES) and tracer-based Laser-Induced Fluorescence (LIF) measurements were performed to study the dynamics of fuel wall-films on the piston top of an optically accessible, four-valve pent-roof GDI research engine for a total of eight operating conditions. Starting from a reference point, the systematic variations include changes in engine speed (600; 1,200 and 2,000 RPM) and load (1000 and 500 mbar intake pressure); concerning the fuel path the Start Of Injection (SOI=360°, 390° and 420° CA after gas exchange TDC) as well as the injection pressure (10, 20 and 35 MPa) were varied. For each condition, 40 experimental images were acquired phase-locked at 10° CA intervals after SOI, showing the wall-film dynamics in terms of spatial extent, thickness and temperature. The simulation framework was developed as follows: first, the spray model was calibrated using spray morphology evolution data of the same injector, characterized in a constant volume spray chamber by high-speed shadow imaging. In a second step, the wall impingement and film models were calibrated using the reference condition. With the model constants now fixed, simulations were run for the remaining operating points and results were compared with the experimental data. The simulations captured all trends observed experimentally, with good quantitative in the transient films' spatial extents and thicknesses.

Water films and droplets on surfaces are important in the design of various processes. In the present work, two complementary non-invasive imaging techniques, laser-induced fluorescence (LIF) and near-infrared absorption (NIRA), were used simultaneously to quantify the deposited water mass in a simple spray-onto-plate experiment. LIF was applied in epiillumination with optical access from only one direction, but it requires the addition of a marker substance to the non-fluorescing water. Here, anisole (methoxybenzene) was used for this purpose. The present implementation of NIRA is based on the intensity ratio of light transmitted through the sample at two wavelengths, 1450 and 600 nm. Since water itself is the IR absorber, a tracer is not required. In a first step, in a thin-film cuvette the influence of temperature and film thickness on the measurement accuracy was investigated for both techniques. In a second set of experiments, water was sprayed onto a hot or cold quartz glass plate and simultaneously imaged with both techniques. From the measurements, advantages and weaknesses of both approaches were identified.