Garnet single-grain analysis is an often used and well established tool in sedimentary provenance studies, especially when metamorphic source rocks are involved. So far, however, solely the geochemical composition of detrital garnets is considered to draw conclusions concerning probable source rocks. The gained information is often limited by (i) geochemical overlap of garnets derived from different lithology and metamorphic grade, (ii) similar probabilities of belonging to more than one source rock type, and (iii) the limitations of discriminating different protolith compositions. Here we present the first attempt of using mineral inclusions in detrital 2 garnet as a provenance tool. We analyzed the inclusions of ~300 fine to medium sand-sized detrital garnets from two proximal modern sand samples taken in the HP/UHP Western Gneiss Region of SW Norway. All mineral inclusions ≥2 µm were identified by Raman spectroscopy, showing that (i) most garnets from HP/UHP metamorphic source rocks contain mineral inclusions ≥2 µm, (ii) Raman spectroscopy is a very powerful tool to characterize the inclusion types, and (iii) less stable mineral phases like kyanite, omphacite, diopside, enstatite, coesite, amphibole group, and epidote group minerals occur as inclusions in garnet. These minerals, which are important for provenance studies, can thus be preserved in the sedimentary record as long as garnet is stable. The combination of inclusion types in garnet and geochemical garnet classification shows that (i) inclusions well reflect the geological characteristics of the sampled catchments, implying that they are useful indicators for HP/UHP provenance, and (ii) inclusions in garnet can be used to support and enhance the provenance information obtained by garnet geochemistry.
Detrital coesite-bearing garnet is the final product of a complex geological cycle including coesite entrapment at ultra-high-pressure conditions, exhumation to Earth’s surface, erosion and sedimentary transport. In contrast to the usual enrichment of high-grade metamorphic garnet in medium- to coarse-sand fractions, coesite-bearing grains are often enriched in the very-fine-sand fraction. To understand this imbalance, we analyse the role of source-rock lithology, inclusion size, inclusion frequency and fluid infiltration on the grain-size heterogeneity of coesite-bearing garnet based on a dataset of 2100 inclusion-bearing grains, of which 93 contain coesite, from the Saxonian Erzgebirge, Germany. By combining inclusion assemblages and garnet chemistry, we show that (1) mafic garnet contains a low number of coesite inclusions per grain and is enriched in the coarse fraction, and (2) felsic garnet contains variable amounts of coesite inclusions per grain, whereby coesite-poor grains are enriched in the coarse fraction and coesite-rich grains extensively disintegrated into smaller fragments resulting in an enrichment in the fine fraction. Raman images reveal that: small coesite inclusions of dimension < 9 µm are primarily monomineralic, whereas larger inclusions partially transformed to quartz; and garnet fracturing, fluid infiltration and the coesite-to-quartz transformation is a late process during exhumation taking place at c. 330°C. A model for the disintegration of coesite-bearing garnet enables the heterogeneous grain-size distribution to be explained by inclusion frequency. High abundances of coesite inclusions cause a high degree of fracturing and fracture connections to smaller inclusions, allowing fluid infiltration and the transformation to quartz, which in turn further promotes garnet disintegration.
Contrasting metamorphic conditions determined by chemical geothermobarometric investigations of ultrahigh-pressure (UHP) lenses surrounded by high-pressure (HP) and medium-pressure (MP) 2 felsic country rocks are an enigmatic feature of UHP terranes. One of the major questions arising is whether the UHP lenses and the country rocks are a product of different peak metamorphic conditions corresponding to different maximum depth or whether country rocks also experienced UHP conditions but equilibrated and/or re-equilibrated at a different metamorphic stage. Here we address this question to the central Saxonian Erzgebirge in the northwestern Bohemian massif, Germany. In order to screen the variety of garnet from lithologies occurring in the study area, we analyzed the detrital garnet record from seven modern stream sands. In addition to 700 inclusionbearing garnet grains previously studied from the 125-250 µm grain-size fraction, we analyzed the 63-125 and 250-500 µm fractions and extended the dataset to overall 2100 inclusion-bearing grains. The new findings of coesite and diamond inclusions in several garnet grains, which are in compositional contrast to garnet of the known UHP lenses but match with those of the felsic country rocks, show that considerable parts of the country rocks underwent UHP metamorphism.Melt inclusions containing cristobalite, kokchetavite, and kumdykolite in garnet derived from the country rocks point to partial melting and re-equilibration during exhumation at HP/HT conditions. Although an amalgamation of rocks which reached different maximum depth may be responsible for some of the contrasting peak metamorphic conditions, the mineralogical evidence for UHP conditions in the felsic country rocks surrounding the UHP lenses proves a largely coherent slab subducted to UHP conditions. Furthermore, the presence of coesite in the subducting voluminous felsic crust and its transformation to quartz during exhumation have great implications for buoyancy development during the metamorphic cycle, which may explain the high exhumation rates of UHP terranes.
Local occurrences of coesite- and diamond-bearing rocks in the central Erzgebirge (northwestern Bohemian Massif, Germany) reveal ultrahigh-pressure (UHP) metamorphic conditions during the Variscan orogeny. Although UHP metamorphism supposedly affected a wider area, implying that rocks that equilibrated under UHP conditions occur dispersed in large volumes of high-pressure country-rock gneisses, mineralogical evidence is scarce. Here we have applied the new concept of capturing the distribution and characteristics of UHP rocks by analyzing inclusions in detrital garnet. Out of 700 inclusion-bearing garnets from seven modern sand samples from creeks draining the UHP area around the Saidenbach reservoir, we detected 26 garnets containing 46 mainly monomineralic coesite inclusions and 22 garnets containing 41 diamond inclusions. Combining these results with geochemical classification of the host garnets, we show (1) that coesite-bearing rocks are common and comprise eclogites as well as felsic gneisses, (2) that small inclusion size is a necessary precondition for the preservation of monomineralic coesite, and (3) for the first time, that diamond-bearing crustal rocks can be detected by analyzing the detrital record. Our results highlight the potential of this novel application of sedimentary provenance tools to UHP research, and the necessity of looking at the micrometer scale to find evidence in the form of preserved UHP minerals.
23Detrital heavy minerals commonly document the geological setting in the source area, hence they are 24 widely used in sedimentary provenance analysis. In heavy mineral studies most commonly the 63−125 25 and 63−250 µm grain-size fractions are used. Heavy mineral data and garnet geochemistry of stream 26 sediments and bedrocks from the catchment area draining the Almklovdalen peridotite massif in SW 27Norway reveal that a wider grain-size spectrum needs to be considered to avoid misleading 28 interpretations. The Almklovdalen peridotite massif consists mainly of dunite and harzburgite, as 29 testified by the heavy mineral suite. At the outlet of the main river the heavy mineral spectrum is very 30 monotonous due to dilution by strong influx of olivine. Heavy minerals like apatite and epidote 31 characterising the host gneisses have almost disappeared. MgO-rich almandine garnets are more 32 frequent in the coarser grain-size fractions, whereas MnO-rich almandine garnets are more frequent in 33 the finer grain-size fractions. Garnets with pyrope content exceeding 50 % are only found in the 34 500−1000 µm grain-size fraction. Therefore, the sample location and the selected grain-size fraction 35
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