15Claims of CO 2 leakage at the Kerr farm near the IEAGHG Weyburn-Midale CO 2 Monitoring and Storage 16 project in Saskatchewan, Canada in 2011 presented an opportunity to test years of research in near-17 surface leakage detection in an operational setting. The claim was based on a study conducted by a private 18 consultant that drew criticism from geologic CO 2 storage experts. To assess the origin of the claimed 19 leakage, a soil gas assessment was conducted at the site using a relatively new process-based soil gas 20 approach (Romanak et al., 2012). In order to assess leakage without years of background data or complex 21 statistical analyses, this simple approach uses three fixed soil gas ratios (augmented by isotopic and 22 hydrocarbon data when needed). Using this approach at the Kerr site, the relative contributions of various 23 processes creating soil gas geochemical signatures were determined including: 1) biologic respiration, 2) 24 CH 4 oxidation, 3) CO 2 dissolution/reaction with carbonate, 4) mixing with atmosphere, and 5) CO 2 25 leakage from the storage reservoir. For additional verification, the results of the Kerr assessment were 26 compared to new data collected at the ZERT controlled release site in Bozeman, Montana and published 27 data from a leakage proxy at the Mt. Etna volcano, Italy. The results from the Kerr site show no evidence 28 for CO 2 leakage from the storage reservoir and also verify that a process-based approach can be used to 29 quickly and economically assess leakage above geologic carbon storage sites. In addition, data from the 30 ZERT release suggest quantification of a leakage signal apart from natural processes may be most easily 31 accomplished using a process-based approach.
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