We present a model of DNA electrophoresis in unentangled polymer
solutions based on a
new separation mechanism in which the DNA drags along polymer molecules
it encounters during
migration. Taking into account the deformation and the
hydrodynamic resistance of the polymers in the
flow, the mutual disengagement time of the DNA and the polymer, and the
average number of polymers
dragged by one DNA, we build a self-consistent theory leading to
predictions for the DNA velocity as a
function of the experimental conditions. Our results agree with
the data of Barron et al. (1994), and
important separation regimes are also identified.
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