Antimony was used as a surfactant during solid-source molecular beam epitaxy of AIGaAs layers. A steady-state surface-segregated population of Sb was maintained at the AIGaAs growth surface by providing a continuous Sb2 flux to compensate for loss due to thermal desorption. Above ∼ 650 °C, the incorporation rate of Sb was negligible, thereby allowing the deposition of AlGaAs layers despite the presence of Sb at the surface. A significant improvement in the optical quality of Al0.24Ga0 76As layers was observed by photoluminescence. In addition, extended reflection high energy electron diffraction oscillations and a reduction in Al0.24Ga0.76As surface roughness was observed when Sb was employed as a surfactant.
Upon examination of shape memory alloy (SMA) actuation designs, there are many considerations and methodologies that are common to them all. A goal of CASMART's design working group is to compile the collective experiences of CASMART's member organizations into a single medium that engineers can then use to make the best decisions regarding SMA system design. In this paper, a review of recent work toward this goal is presented, spanning a wide range of design aspects including evaluation, properties, testing, modeling, alloy selection, fabrication, actuator processing, design optimization, controls, and system integration. We have documented each aspect, based on our collective experiences, so that the design engineer may access the tools and information needed to successfully design and develop SMA systems. Through comparison of several case studies, it is shown that there is not an obvious single, linear route a designer can adopt to navigate the path of concept to product. SMA engineering aspects will have different priorities and emphasis for different applications. INTRODUCTIONShape memory alloys (SMAs) have been a topic of significant research interest for over forty years. Microstructural complexities and their resulting thermomechanical properties have presented challenges in understanding how to integrate these materials into structural applications.Consequently, design of structural and mechanical systems involving SMA materials has been sparse and ad hoc. However, upon examination of a variety of system designs, there are many considerations and parameters that are common to them all. The Consortium for the Advancement of Shape Memory Alloy Research and Technology (CASMART) was established to foster sharing of technical knowledge about SMAs, to achieve new understanding of the materials, and to facilitate progress in applying that knowledge. The Design Working Group of CASMART strives to serve as a single location to capture the collective best practices, critical information and perspective necessary for designing systems involving SMA materials and actuators.The objective of this paper is to compile the experiences of the authors into a resource that can aid other engineers in SMA
Few technologies can produce meaningful power from low temperature waste heat sources below 250°C, particularly on a per-mass basis. Since the 1970’s energy crisis, NiTi shape memory alloy (SMA) and associated thermal engines have been considered a viable heat-to-power transducer but were not adopted due to previously poor material quality, low supply, design complexity, and cost. Decades of subsequent material development, research, and commercialization have resulted in the availability of consistently high-quality, well-characterized, low cost alloys and a renewed interest in SMA as a waste heat energy recovery technology. The Lightweight Thermal Energy Recovery System (LighTERS) is an ongoing ARPA-E funded collaboration between General Motors Company, HRL Laboratories, Dynalloy, Inc., and the University of Michigan. In this paper we will present initial results from investigations of a closed loop SMA thermal engine (a refinement of the Dr. Johnson design) using a helical coil element and forced-air heat exchange. This engine generates mechanical power by continuously pulling itself through separate hot and cold air streams using the shape memory phase transformation to alternately expand and contract at frequencies between 0.25 and 2 Hz. This work cycle occurs continuously along the length of the coil loop and produces steady state power against an external moment. We present engine features and the thermal envelope that resulted in devices achieving between 0.1 and 0.5 W/g of shape memory alloy material using only forced air heat exchangers and room temperature cooling.
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