No abstract

Four local-scale sites in areas with similar corn (Zea mays L.) and soybean [Glycine max (L.) Merr.] agriculture were studied to determine the effects of different hydrogeologic settings of the Northern Atlantic Coastal Plain (NACP) on the transport of nutrients and pesticides in groundwater. Settings ranged from predominantly well-drained soils overlying thick, sandy surficial aquifers to predominantly poorly drained soils with complex aquifer stratigraphy and high organic matter content. Apparent age of groundwater, dissolved gases, N isotopes, major ions, selected pesticides and degradates, and geochemical environments in groundwater were studied. Agricultural chemicals were the source of most dissolved ions in groundwater. Specific conductance was strongly correlated with reconstructed nitrate (the sum of N in nitrate and N gas) (R(2) = 0.81, p < 0.0001), and is indicative of the relative degree of agricultural effects on groundwater. Trends in nitrate were primarily related to changes in manure and fertilizer use at the well-drained sites where aquifer conditions were consistently oxic. Nitrate was present in young groundwater but completely removed over time through denitrification at the poorly drained sites where there were variations in chemical input and in geochemical environment. Median concentrations of atrazine (6-chloro-N-ethyl-N'-(1-methylethyl)-1,3,5-triazine-2,4-diamine), metolachlor (2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide), and some of their common degradates were higher at well-drained sites than at poorly drained sites, with concentrations of degradates generally higher than those of the parent compounds at all sites. An increase in the percentage of deethylatrazine to total atrazine over time at one well-drained site may be related to changes in manure application.

What kind of water-quality information does the NAWQA Program provide? Water-quality assessments by a single program cannot possibly address all of the Nation's water-resources needs and issues. Therefore, it is necessary to define the context within which NAWQA information is most useful. • Total resource assessment-NAWQA assessments are long-term and interdisciplinary, and include information on water chemistry, hydrology, land use, stream habitat, and aquatic life. Assessments are not limited to a specific geographic area or water-resource problem at a specific time. Therefore, the findings describe the general health of the total water resource, as well as emerging water issues, thereby helping managers and decision makers to set priorities. • Source-water characterization-Assessments focus on the quality of the available, untreated resource and thereby complement (rather than duplicate) Federal, State, and local programs that monitor drinking water. Findings are compared to drinking-water standards and health advisories as a way to characterize the resource. • Compounds studied-Assessments focus on chemical compounds that have wellestablished methods of investigation. It is not financially or technically feasible to assess all the contaminants in our Nation's waters. In general, the NAWQA Program investigates those pesticides, nutrients, volatile organic compounds, and metals that have been or are currently used commonly in agricultural and urban areas across the Nation. A complete list of compounds studied is on the NAWQA Web site at water.usgs.gov/nawqa. • Detection relative to risk-Compounds are measured at very low concentrations, often 10 to 100 times lower than Federal or State standards and health advisories. Detection of compounds, therefore, does not necessarily translate to risks to human health or aquatic life. However, these analyses are useful for identifying and evaluating emerging issues, as well as for tracking contaminant levels over time. • Multiple scales-Assessments are guided by a nationally consistent study design and uniform methods of sampling and analysis. Findings thereby pertain not only to water quality of a particular stream or aquifer, but also contribute to the larger picture of how and why water quality varies regionally and nationally. This consistent, multiscale approach helps to determine if a water-quality issue is isolated or pervasive. It also allows direct comparisons of how human activities and natural processes affect water quality in the Nation's diverse environmental settings.

L i t t l e P o n d G r e a t P o n d G r e e n P o n d B o u r n e s P o n d Nantucket SoundCover photo. View northward from above Nantucket Sound of the narrow coastal saltwater embayments, referred to as coastal ponds, in southern Falmouth, Cape Cod, Massachusetts, and several freshwater ponds 2 to 4 miles inland from the coast. The Massachusetts Military Reservation is the tan area in the top right of the photo. Photography by Joseph R. Melanson, Aerials Only (http://www.skypic.com), used with permission. For more information on the USGS-the Federal source for science about the Earth, its natural and living resources, natural hazards, and the environment, visit http://www.usgs.gov or call 1-888-ASK-USGS. Transport of Nitrogen in a TreatedFor an overview of USGS information products, including maps, imagery, and publications, visit http://www.usgs.gov/pubprodTo order this and other USGS information products, visit http://store.usgs.gov Any use of trade, product, or firm names is for descriptive purposes only and does not imply endorsement by the U.S. Government.Although this report is in the public domain, permission must be secured from the individual copyright owners to reproduce any copyrighted materials contained within this report. Horizontal coordinate information is referenced to the North American Datum of 1927 (NAD 27).Altitude, as used in this report, refers to distance above the vertical datum.Specific conductance is given in microsiemens per centimeter at 25 degrees Celsius (µS/cm at 25°C). Concentrations AbstractLand disposal of treated wastewater from a treatment plant on the Massachusetts Military Reservation in operation from 1936 to 1995 has created a plume of contaminated groundwater that is migrating toward coastal discharge areas in the town of Falmouth, Massachusetts. To develop a better understanding of the potential impact of the treated-wastewater plume on coastal discharge areas, the U.S. Geological Survey, in cooperation with the Air Force Center for Engineering and the Environment, evaluated the fate of nitrogen (N) in the plume. Groundwater samples from two large sampling events in 1994 and 2007 were used to map the size and location of the plume, calculate the masses of nitrate-N and ammonium-N, evaluate changes in mass since cessation of disposal in 1995, and create a gridded dataset suitable for use in nitrogen-transport simulations. In 2007, the treated-wastewater plume was about 1,200 meters (m) wide, 30 m thick, and 7,700 m long and contained approximately 87,000 kilograms (kg) nitrate-N and 31,600 kg total ammonium-N. An analysis of previous studies and data from the 1994 and 2007 sampling events suggests that most of the biologically reactive nitrogen in the plume in 2007 will be transported to coastal discharge areas as either nitrate or ammonium with relatively little transformation to an environmentally nonreactive end product such as nitrogen gas.Nitrogen-transport simulations were conducted with a previously calibrated regional three-dimensional MODFLOW groundwate...

vii 18. Graph showing range of chloride concentrations estimated from specificconductance values measured at 1-minute intervals in highway runoff during runoff events with one or more estimated values that exceed the 230-milligramsper-liter criterion continuous concentration for chloride in receiving waters at U.S. Geological Survey monitoring station 423027071291301 along State Route 2 in Littleton, Massachusetts, during the period from