Rechargeable aqueous proton batteries are promising competitors for the next generation of energy storage systems with the fast diffusion kinetics and wide availability of protons. However, poor cycling stability is a big challenge for proton batteries due to the attachment of water molecules to the electrode surface in acid electrolytes. Here, a hydrogen‐bond disrupting electrolyte strategy to boost proton battery stability via simultaneously tuning the hydronium ion solvation sheath in the electrolyte and the electrode interface is reported. By mixing cryoprotectants such as glycerol with acids, hydrogen bonds involving water molecules are disrupted leading to a modified hydronium ion solvation sheaths and minimized water activity. Concomitantly, glycerol absorbs on the electrode surface and acts to protect the electrode surface from water. Fast and stable proton storage with high rate capability and long cycle life is thus achieved, even at temperatures as low as −50 °C. This electrolyte strategy may be universal and is likely to pave the way toward highly stable aqueous energy storage systems.

The complex behaviour of layered oxide cathode materials at high voltages currently limits the energy densities which can be achieved by sodium-ion batteries.

Based on our rational approach to stoichiometric selection, we present two high performance Na-ion cathode materials: P2-Na2/3Mn0.9−xNixTi0.05Fe0.05O2 (x = 0.10 and 0.20).