It has been suggested that liming can improve soil structure and thereby decrease losses of particles and associated nutrients. In this study, two types of structure lime, slaked lime (Ca(OH)2) and a mixed product of calcium carbonate (CaCO3) and slaked lime (Ca(OH)2), were applied at three different rates in field trials on clayey soils (24-40% clay). A combination of primary tillage and structure liming was also studied, in a split-plot trial on a clayey soil (25% clay). Aggregate (2-5 mm) stability, measured as reduction in turbidity (which is strongly correlated with losses of particulate phosphorus), was significantly increased with the highest application rates of both structure lime products. Aggregate size distribution was also improved with structure lime, creating a finer tilth in the seedbed. Yield response to structure lime was not consistent, with both negative and positive responses over the four-year study period. Positive yield responses can possibly be attributed to the finer tilth preventing evaporation in two dry growing seasons. Negative yield responses were probably an effect of impaired phosphorus availability associated with limited precipitation in

Context. In Sweden, mixtures of 80-85% ground limestone and 15-20% slaked lime (hereafter, 'structure lime') are used in subsidised environmental schemes to improve aggregate stability and mitigate phosphorus losses on clay soils. Aims. This study investigated different rates of structure lime application and soil variables on aggregate stability on clay soils, and whether soil properties can predict aggregate stability following structure liming. Methods. Increasing application rates of 0-16 t ha −1 of structure lime (SL0, SL4, SL8 and SL16) were tested in 30 field trials in Sweden. Soil aggregates (2-5 mm) were collected 1 year after liming and subjected to two rainfall events in a rain simulator. Key results. Leachate turbidity after the second simulated rainfall event decreased significantly (13% and 20%, respectively, in SL8 and SL16) compared with SL0, indicating improved aggregate stability. There was a near-significant interaction (P = 0.056) between treatment and trial. Grouping by initial pH ðH 2 OÞ (range 6.2-8.3), clay content (10-61%), soil organic matter content (SOM, 2.2-7.1) and clay mineralogy (SmV index, 0.2-3.8) revealed different effects on turbidity. Discriminant analysis of soil characteristics and four tillage variables correctly classified the outcome for 27 of the 30 trial sites. Conclusions. Results show that structure liming can improve aggregate stability 1 year after liming, and can thereby prevent particulate P losses from soils with high clay and SOM content, low SmV index and low initial pH. The discriminant analysis also showed the importance of tillage for the outcome of structure liming. Implications. Clay soil characteristics such as SOM and pH significantly affected aggregrate stability after structure liming.

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Two dates (early, normal) for application and incorporation of structure lime to clay soil were examined at four field sites, to test whether early liming had more favourable effects on aggregate stability. Aggregate size distribution measurements revealed a finer tilth at the early liming date (20 August) than the normal date (14 September). Aggregate stability estimated one year later, using as a proxy turbidity in leachate from 2–5 mm aggregates subjected to two simulated rainfall events, was significantly improved (11% lower turbidity) with early compared with normal liming date. Three years after structure liming, soil structural stability measurements on lysimeters (15 cm high, inner diameter 18 cm) subjected to repeated simulated rainfall events showed no significant differences in turbidity in leachate between the early and normal liming dates. However, there was a strong interaction between liming date and site indicating different reactions at different sites. Our results suggest that early spreading and incorporation can improve the success of structure liming, but only if soil conditions are favourable.

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