Air-stable,
ambipolar heterojunction-based organic light-emitting
field-effect transistors (OLEFETs) with a top-contact, multidigitated,
long-channel geometry were produced, and the current–voltage–light
emission (I–V–L) characteristics were
systematically examined. Two active
layers of p-type pentacene and n-type N,N′-ditridecylperylene-3,4,9,10-tetra
carboxylic diimide (P13) as well as a protecting layer of 2,5-bis(4-biphenyl)
thiophene (BP1T) were successively
deposited using the neutral cluster beam deposition method. On the
basis of the growth of high-quality, well-packed crystalline thin
films, the OLEFETs demonstrated good field-effect characteristics,
well-balanced ambipolarity, operational stability, and electroluminescence
(EL) under ambient conditions. The operating conduction and EL mechanisms
responsible for the observed recombination zone are discussed with
the aid of light-emission images obtained using a charge-coupled device.
Realization of size controllable graphene micro/nanogap with a micro/nanowire mask method for organic fieldeffect transistors Appl. Phys. Lett. 99, 103301 (2011); 10.1063/1.3634065 Influence of gate dielectrics on the performance of single-layered organic transistors and bi-layered organic lightemitting transistors prepared by the neutral cluster beam deposition methodThe neutral cluster beam deposition (NCBD) method has been applied to the production and characterization of ambipolar, heterojunction-based organic light-emitting field-effect transistors (OLEFETs) with a top-contact, multi-digitated, long-channel geometry. Organic thin films of n-type N,N 0 -ditridecylperylene-3,4,9,10-tetracarboxylic diimide and p-type copper phthalocyanine were successively deposited on the hydroxyl-free polymethyl-methacrylate (PMMA)-coated SiO 2 dielectrics using the NCBD method. Characterization of the morphological and structural properties of the organic active layers was performed using atomic force microscopy and X-ray diffraction. Various device parameters such as hole-and electron-carrier mobilities, threshold voltages, and electroluminescence (EL) were derived from the fits of the observed current-voltage and current-voltage-light emission characteristics of OLEFETs. The OLEFETs demonstrated good field-effect characteristics, well-balanced ambipolarity, and substantial EL under ambient conditions. The device performance, which is strongly correlated with the surface morphology and the structural properties of the organic active layers, is discussed along with the operating conduction mechanism. V C 2014 AIP Publishing LLC. [http://dx.
In this paper, we report on the fabrication and electrical characterization of top-contact, ambipolar organic field-effect transistors (OFETs) and inverters based upon a heterostructure of p-type pentacene on n-type N,N′-ditridecylperylene-3,4,9,10-tetracarboxylic di-imide (P13), using the neutral cluster beam deposition (NCBD) method. The device characteristics measured as a function of both P13 and pentacene layer thicknesses revealed that OFETs with thicknesses of P13 (300 Å) and pentacene (200 Å) showed high air-stability and well-balanced ambipolarity with hole and electron mobilities of 0.12 and 0.08 cm2/V s. The complementary inverters, comprising two identical ambipolar OFETs, were found to operate both in the first and third quadrants of the transfer curves and exhibited a high voltage inversion gain of 13, good noise margins, and little hysteresis under ambient conditions. The results presented demonstrate that the NCBD-based ambipolar transistors and inverters qualify them as promising potential candidates for the construction of high-performance, organic thin film-based integrated circuits.
In this study, heterojunction-based organic light-emitting field-effect transistors (OLEFETs) with a top-contact, long-channel geometry were fabricated and comparatively characterized. The neutral cluster beam deposition (NCBD) method was used to successively deposit two layers of p-type pentacene and n-type tris(8-hydroxyquinoline) aluminum (Alq 3 ). For doped OLEFETs, 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran (DCM) was used as a highly fluorescent dye dopant to enhance the light-emission efficiency and change the emission color. OLEFETs revealed fine device characteristics based on deposition of highly crystalline active layers. The combination of the highly fluorescent DCM-doping and asymmetric electrode configuration (Au and Li:Al or LiF/Al) exhibited efficient energy transfer, enhanced electroluminescence (EL) emission. The operating light-emission mechanisms were discussed based on EL photos acquired using a charge-coupled device (CCD) camera.
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