Deaggregation of oxidized ultradispersed diamond (UDD) in dimethylsulfoxide followed by reaction with glycidol monomer, purification via aqueous dialysis, and dispersion in ethylene glycol (EG) base fluid affords nanodiamond (ND)-poly(glycidol) polymer brush:EG nanofluids exhibiting 12% thermal conductivity enhancement at a ND loading of 0.9 vol %. Deaggregation of UDD in the presence of oleic acid/octane followed by dispersion in light mineral oil and evaporative removal of octane gives ND·oleic acid:mineral oil dispersions exhibiting 11% thermal conductivity enhancement at a ND loading of 1.9 vol %. Average particle sizes of ND additives, determined by dynamic light scattering, are, respectively, ca. 11 nm (in H2O) and 18 nm (in toluene). Observed thermal conductivity enhancements outperform enhancement effects calculated using Maxwell's effective medium approximation by 2- to 4-fold. Covalent ND surface modification gives 2-fold greater thermal conductivity enhancement than ND surface modification via hydrogen-bonding interactions at similar concentrations. Stable, static ND:mineral oil dispersions are reported for the first time.

Floodplains, paleosols, and antecedent landforms near the apex of the Brahmaputra fan delta in north-central Bangladesh preserve cycles of fluvial sediment deposition, erosion and weathering. Together these landforms and their associated deposits comprise morphostratigraphic units that define the river's history and have influenced its channel position and avulsion behaviour through the Late Quaternary. Previously, temporal differentiation within these units has not been sufficient to decipher their sequence of deposition, an important step in understanding the spatial pattern of migration of the Brahmaputra River. Holocene units in this region are fairly well established by radiocarbon dating of in situ organic material, but pre-Holocene units are considered Pleistoceneaged if organic material is dated >48 000 year BP (the limit of radiocarbon dating) or the sediments are positioned beneath a prominent paleosol, interpreted as a buried soil horizon that developed during a previous sea level lowstand. In such cases, these morphostratigraphic units have been broadly interpreted as Pleistocene without knowing their absolute depositional ages or relative evolutionary chronology. Here we use detailed sediment analysis to better differentiate morphostratigraphic units at the Brahmaputra's avulsion node, establishing the sequence of deposition and subsequent weathering of these bodies. We then test this relative chronology by luminescence dating of the sands beneath these landform surfaces. This work provides the first absolute depositional age constraints of terrace sediments for the Middle to Late Pleistocene Brahmaputra River and upper Bengal basin. The luminescence ages are complemented by detailed compositional trends in the terrace deposits, including clay mineralogy and the degree of weathering. Together, these newly dated and carefully described morphostratigraphic units reflect eustasy-driven cycles of terrace development by way of highstand floodplain deposition and subsequent lowstand exposure and weathering, along with active tectonic deformation. Defining this Late Quaternary history of terrace development and position of the Brahmaputra River is a first step toward an integrated understanding of basin and delta evolution over multiple glacioeustatic cycles and tectonically relevant timescales.

The interface between photoactive biological materials with two distinct semiconducting electrodes is challenging both to develop and analyze. Building off of our previous work using films of photosystem I (PSI) on p-doped silicon, we have deposited a crystalline zinc oxide (ZnO) anode using confined-plume chemical deposition (CPCD). We demonstrate the ability of CPCD to deposit crystalline ZnO without damage to the PSI biomaterial. Using electrochemical techniques, we were able to probe this complex semiconductor-biological interface. Finally, as a proof of concept, a solid-state photovoltaic device consisting of p-doped silicon, PSI, ZnO, and ITO was constructed and evaluated.

REPO4–BG composites synthesized by a new 1-step method were investigated and were found to be similar to the composite made by the traditional 2-step method.