There is significant interest in biodegradable and transparent UV protection films from renewable resources for many different applications. Herein, the preparation and characterization of semitransparent flexible cellulose films containing low amounts of covalently bonded lignin with UV-blocking properties are described. Azide modified cellulose dissolved in dimethylacetamide/lithium chloride (DMAc/LiCl) was reacted with propargylated lignin to produce 0.5%, 1%, and 2% by weight lignin containing materials. Cellulose-lignin films were prepared by regeneration in acetone. These covalently bonded cellulose-lignin films were homogeneous, unlike the simple blends of cellulose and lignin. Prepared films showed high UV protection ability. Cellulose film containing 2% lignin showed 100% protection of UV-B (280–320 nm) and more than 90% of UV-A (320–400 nm). The UV protection of prepared films was persistent when exposed to thermal treatment at 120 °C and UV irradiation. Thermogravimetric analysis of the films showed minimal mass loss up to 275 °C. The tensile strength of the neat cellulose film was around 120 MPa with about a 10% strain to break. Treated cellulose films with 2% lignin showed lower tensile strength (90 MPa). The described methods demonstrate a straightforward procedure to produce renewable based cellulose-lignin UV-light-blocking films.

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Atomic layer deposition (ALD) of aluminum oxide on nonwoven polypropylene and woven cotton fabric materials can be used to transform and control fiber surface wetting properties. Infrared analysis shows that ALD can produce a uniform coating throughout the nonwoven polypropylene fiber matrix, and the amount of coating can be controlled by the number of ALD cycles. Upon coating by ALD aluminum oxide, nonwetting hydrophobic polypropylene fibers transition to either a metastable hydrophobic or a fully wetting hydrophilic state, consistent with well-known Cassie-Baxter and Wenzel models of surface wetting of roughened surfaces. The observed nonwetting/wetting transition depends on ALD process variables such as the number of ALD coating cycles and deposition temperature. Cotton fabrics coated with ALD aluminum oxide at moderate temperatures were also observed to transition from a natural wetting state to a metastable hydrophobic state and back to wetting depending on the number of ALD cycles. The transitions on cotton appear to be less sensitive to deposition temperature. The results provide insight into the effect of ALD film growth mechanisms on hydrophobic and hydrophilic polymers and fibrous structures. The ability to adjust and control surface energy, surface reactivity, and wettability of polymer and natural fiber systems using atomic layer deposition may enable a wide range of new applications for functional fiber-based systems.

Inkjet printing of functional inks on textiles to embed passive electronics devices and sensors is a novel approach in the space of wearable electronic textiles. However, achieving functionality such as conductivity by inkjet printing on textiles is challenged by the porosity and surface roughness of textiles. Nanoparticle-based conductive inks frequently cause blockage/clogging of inkjet printer nozzles, making it a less than ideal method for applying these functional materials. It is also very challenging to create a conformal conductive coating and achieve electrically conductive percolation with the inkjet printing of metal nanoparticle inks on rough and porous textile and paper substrates. Herein, a novel reliable and conformal inkjet printing process is demonstrated for printing particle-free reactive silver ink on uncoated polyester textile knit, woven, and nonwoven fabrics. The particle-free functional ink can conformally coat individual fibers to create a conductive network within the textile structure without changing the feel, texture, durability, and mechanical behavior of the textile. It was found that the conductivity and the resolution of the inkjet-printed tracks are directly related with the packing and the tightness of fabric structures and fiber sizes of the fabrics. It is noteworthy that the electrical conductivity of the inkjet-printed conductive coating on pristine polyethylene terephthalate fibers is improved by an order of magnitude by in situ heat-curing of the textile surface during printing as the in situ heat-curing process minimizes the wicking of the ink into the textile structures. A minimum sheet resistance of 0.2 ± 0.025 and 0.9 ± 0.02 Ω/□ on polyester woven and polyester knit fabrics is achieved, respectively. These findings aim to advance E-textile product design through integration of inkjet printing as a low-cost, scalable, and automated manufacturing process.