A microplasma-based optical emission spectrometry (OES) system has emerged as a potential tool for field analysis of heavy metal pollution due to its features of portability and low energy consumption, while the development of an efficient sample introduction approach against matrix interference is crucial to meet the requirements of complex sample analysis. Herein, a MoS2–covalent organic framework (COF) composite serves as a bifunctional supporter for efficient sample separation/enrichment and photochemical vapor generation (PVG) enhancement, thereby achieving highly selective and sensitive detection of heavy metals in environmental water by dielectric barrier discharge (DBD) microplasma-OES. With trace nickel analysis as a model, the MoS2-COF composite with a large specific surface area and a porous structure can not only efficiently separate and enrich nickel ions from a sample matrix through electrostatic interaction and coordination to reduce the interference of coexisting ions but also significantly improve the subsequent PVG efficiency due to the formed heterojunction and more negative reduction potential. Under optimized conditions, a linear range of 0.1–10 μg L–1 along with a detection limit of 0.03 μg L–1 is obtained for nickel. Compared with direct PVG, the tolerance to coexisting ions is greatly enhanced, and the detection limit is also improved by 43-fold. The accuracy and practicability of the present PVG-DBD-OES system are verified by measuring several certified reference materials and real water samples. MoS2-COF as a bifunctional supporter promotes the performance of the PVG-DBD-OES system in terms of anti-interference ability and detection sensitivity, especially for robust and efficient on-site analysis of complex samples.

Pulse-jet cleaned fabric filters are commonly used for air pollution control in many industries. Pulse-jet cleaning is widely used for this purpose as it enables frequent cleaning while the filter is operating. However, the theoretical system of the forming mechanism of the pulse-jet cleaning has not formed so far. This indicates the theoretical model plays an important role in designing effective pulse-jet cleaned fabric filters.