This review presents the recent developments in the research hotspots of advanced functional polymers; their concepts, design strategies, and applications are briefly discussed.
For
the constant demand of organic light-emitting diodes (OLEDs)
with high efficiency, long lifetime, and low cost for display and
lighting applications, the development of high-performance organic
electroluminescence materials is key. Aggregation-induced emission
(AIE) luminogens (AIEgens) provide a promising choice for their excellent
performance in nondoped devices. Here we report a multifunctional
deep blue AIE material, which can be used not only as an excellent
blue emitter but also as a good host of green/orange/red phosphors.
A deep blue nondoped OLED with a CIE
y
of
0.08 and high external quantum efficiency (EQE) of 7.0% is achieved.
Furthermore, a series of green/orange/red phosphorescent OLEDs with
high efficiency and low roll-off are obtained. Impressively, hybrid
white OLEDs (WOLEDs) based on the deep blue AIEgen exhibit simultaneously
high CRI (>90), excellent efficiency (EQEmax> 25%,
PEmax = 99.9 lm W–1 for two-color WOLEDs,
PEmax = 60.7 lm W–1 for four-color WOLEDs),
low roll-off (PE1000nit = 72.1 lm W–1 for two-color WOLEDs, PE1000nit = 43.5 lm W–1 for four-color WOLEDs), and superior stable color, indicative of
the multifunction of AIEgens. Accordingly, this work opens a new direction
for achieving high-performance OLEDs, particularly offering a smart
but simple way to depress the efficiency roll-off and reduce the cost
of OLEDs for practical applications.
Sulfide‐based all‐solid‐state batteries (ASSBs) are one of the most promising energy storage devices due to their high energy density and good safety. However, due to the volume (stress) changes of the solid active materials during the charging and discharging process, the generation and evolution of electrochemomechanical stresses are becoming serious and unavoidable problems during the operation of all‐solid‐state batteries due to the lack of a liquid electrolyte to partially buffer the stress generated in the electrodes. To understand these electrochemo‐mechanical effects, including the origins and evolution of mechanical or internal stresses, it is necessary to develop some highly sensitive probing techniques to measure them precisely and bridge the relationship between the electrochemical reaction process and internal stress evolution. Herein, recent progress on uncovering the origins of the internal stresses, the working principle and experimental devices for stress measurement, and the application of those stress‐measuring techniques in the study of electrochemical reactions in sulfide‐based ASSBs are briefly summarized and overviewed. The investigation of precise and operando monitoring techniques and strategies for suppressing or relaxing these electrochemomechanical stresses will be an important direction in future solid‐state batteries.
AIE polymers pTPE-DPA-Cz and pTPE-DPA-Flu are synthesized and used as emitting layers in doped and non-doped polymeric LEDs through a solution process, and show maximum EQE of 3.26% in the doped PLEDs and CE of 3.69 cd A−1 for the non-doped PLEDs and low efficiency roll-off.
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