A photocatalytic C-H gem-difunctionalization of 1,3-benzodioxoles with two different alkenes for the synthesis of highly functionalized monofluorocyclohexenes is desribed. Using 4CzIPN as the photocatalyst, the direct single electron oxidation of...
Herein, we describe a photocatalytic defluorinative ring-opening gem-difluoroallylation of cycloalkanols for the synthesis of gem-difluoroalkenes bearing a distal carbonyl group. The reaction proceeds with the generation of alkoxy radicals via...
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