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Droplet‐based triboelectric nanogenerators (D‐TENGs) have recently gained much attention due to their great potential in harvesting energy. However, the output performance of conventional single‐electrode droplet‐based TENGs is limited owing to low induced electrification efficiency. The asymmetric distribution of electric fields on both sides of the electrode edge enhances the electrostatic induction process and improves the output performance of D‐TENG. Herein, an induced electrification‐enhanced droplet‐based triboelectric nanogenerator (IED‐TENG) is developed to effectively enhance the output performance by simultaneously optimizing the electrode structure and the dynamics of the water droplet. One droplet falling from a height of 30 cm results in a −70 V output voltage and −6 µA short‐circuit current, which is 70 times and 20 times the full‐inductive‐electrode mode, respectively. The working principle and the relationship between electric signal and droplet dynamics are analyzed in detail. Moreover, the peak output voltage can reach −110 V, and the peak current can get −140 µA by using the power generation of multiple water droplets. The present protocol provides an easy and reproducibility strategy in energy harvesting and sensing areas.

Micro/nano-AAO was fabricated on the surface of Al, and the short-circuit current was reduced 8.77 times through microstructure and composition regulation. Besides, a positive correlation between the contact area and the charge density was demonstrated.