Eight new dimeric sesquiterpene lactones (japonicones E-L, 1- 8), including a novel sesquiterpene dimer bearing a rare hydroperoxide group (japonicone E, 1), were isolated from the aerial part of Inula japonica Thunb. Their structures were determined mainly by the use of 1D and 2D NMR spectroscopic techniques including HSQC, (1)H-(1)H COSY, HMBC, and NOESY. All the isolates were tested for inhibitory effects against LPS-induced NO production in RAW264.7 macrophages. Among the compounds tested, japonicone F (2) showed the strongest activity with the IC(50) value of 4.1 microg/mL.
Flexible electrodes have attracted much attention in consumer electronic applications. In this work, laser direct writing is used to fabricate copper/graphene composite electrodes on a flexible substrate in one step. This direct writing process with a low power laser can reduce copper ions in thin films to form copper nanomaterials and spontaneously interconnect them to gain good conductivity, while the laser also induces the growth of multi-layer graphene that coats on copper to improve the oxidation resistance of electrodes. The electrical performance and chemical composition of flexible electrodes can be tuned by laser power, scanning speed, and defocus distance. A mechanism of in situ reduction and interconnection of copper nanomaterials during laser direct writing has been proposed. This method could largely reduce the oxidation issue by avoiding synthesis and sintering processes of copper nanomaterials. These as-written copper electrodes have good stability and have potential applications in flexible electronics, such as flexible heaters or antennas as demonstrated.
Flexible
electrodes have broad applications in microelectronics.
In this work, flexible electrodes were fabricated through chemically
induced joining of silver nanoparticles at room temperature. After
the joining process, the resistance of the silver track decreased
by 8 orders of magnitude. The joining parameters were systematically
investigated including the concentration of the chemical solution,
sintering time, and drying temperature. This chemical method achieved
the same effect at room temperature as compared to the methods using
thermal sintering. The changes of the microstructure and the surface
composition of silver nanoparticles were characterized to better understand
the nanojoining process at room temperature.
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