Abstract. Winter has the worst air pollution of the year in the megacity of Beijing. Despite extensive winter studies in recent years, our knowledge of the sources, formation mechanisms and evolution of aerosol particles is not complete. Here we have a comprehensive characterization of the sources, variations and processes of submicron aerosols that were measured by an Aerodyne high-resolution aerosol mass spectrometer from 17 December 2013 to 17 January 2014 along with offline filter analysis by gas chromatography/mass spectrometry. Our results suggest that submicron aerosols composition was generally similar across the winter of different years and was mainly composed of organics (60 %), sulfate (15 %) and nitrate (11 %). Positive matrix factorization of high- and unit-mass resolution spectra identified four primary organic aerosol (POA) factors from traffic, cooking, biomass burning (BBOA) and coal combustion (CCOA) emissions as well as two secondary OA (SOA) factors. POA dominated OA, on average accounting for 56 %, with CCOA being the largest contributor (20 %). Both CCOA and BBOA showed distinct polycyclic aromatic hydrocarbons (PAHs) spectral signatures, indicating that PAHs in winter were mainly from coal combustion (66 %) and biomass burning emissions (18 %). BBOA was highly correlated with levoglucosan, a tracer compound for biomass burning (r2 = 0.93), and made a considerable contribution to OA in winter (9 %). An aqueous-phase-processed SOA (aq-OOA) that was strongly correlated with particle liquid water content, sulfate and S-containing ions (e.g. CH2SO2+) was identified. On average aq-OOA contributed 12 % to the total OA and played a dominant role in increasing oxidation degrees of OA at high RH levels (> 50 %). Our results illustrate that aqueous-phase processing can enhance SOA production and oxidation states of OA as well in winter. Further episode analyses highlighted the significant impacts of meteorological parameters on aerosol composition, size distributions, oxidation states of OA and evolutionary processes of secondary aerosols.

Trends in Chinese global radiation, direct horizontal radiation, diffuse radiation, clearness index, diffuse fraction and percentage of possible sunshine duration for the period 1961–2000 were evaluated based on data for daily surface solar radiation and monthly sunshine duration. Annual means for all six variables were calculated for each station and for China as a whole. Linear regression analysis was used to characterize long‐term annual trends in these variables. Over the latter half of the 20th century, there have been significant decreases in global radiation (−4.5 W/m2 per decade), direct radiation (−6.6 W/m2 per decade), clearness index (−1.1% per decade), and the percentage of possible sunshine duration (−1.28% per decade), but diffuse fraction has increased (1.73% per decade). Although there is some evidence that conditions have improved in the last decade, the consistent spatial and temporal variations of these variables support the theory that increased aerosol loadings were at least partially responsible for the observed decreases in global radiation and direct radiation, the clearness index, and the monthly percentage of possible sunshine duration over much of China.

Preliminary schematics of polarimetric signatures at low levels in southern plains classic supercells are developed for pretornado, tornado, and tornado demise times from a small collection of cases, most of which are cyclic tornado producers. Characteristic signatures and patterns are identified for the reflectivity factor (Z HH ), the differential reflectivity (Z DR ), the correlation coefficient ( hv ), and the specific differential phase (K DP ). Signatures likely related to an ongoing tornado are also discussed. Major findings in Z HH at tornado times include "wings" of higher values often extending away from the updraft region, a stronger gradient on the west side of the echo appendage, and a local maximum at the storm location favorable for tornadogenesis. Increasing cyclonic curvature of the hook-echo region was noted through the tornado life cycle. The Z DR tended to indicate hail shafts most commonly at tornado times, with the highest storm values typically located along the storm's forward flank throughout the tornado life cycle. A Z DR minimum often occurred at the tornado-favorable location, while low Z DR occasionally trailed the tornado region. Stormminimum hv typically occurred at the tornado-favorable location at tornado times and in hail shafts or heavy rain areas at other times. Another region of low correlation was the storm updraft, while the highest storm correlation was typically found in the downwind light-precipitation shield. The K DP typically exhibited a storm-core temporal maximum at tornado times, with the highest storm values in regions of hail and heavy rain and the lowest values in the downwind light-precipitation region. Values in the tornadofavorable region were typically near zero and sometimes strongly negative.