High‐Al chromite from the Kudi chromitites contains a wide range of mineral inclusions. They include clinopyroxene, amphibole, phlogopite, olivine, orthopyroxene, apatite, base‐metal sulfides, calcite and brucite. The modal abundance of inclusions vary greatly among different grains of chromite. The common inclusions are clinopyroxene and amphibole, which occur as monomineral or polymineral associated with other minerals. The shapes of these inclusions tend to follow the growth plane of host chromite. Mineral assemblages and textures demonstrate that some inclusions (olivine, clinopyroxene) are trapped during magmatic stage, and most of the inclusions (e.g., amphibole, phlogopite) are trapped during recrystallization of chromite. Sulfide inclusions are pentlandite, chalcopyrite and cubanite. They occur either as isolated grains or together with silicate minerals, and formed from the separation of sulfide‐bearing liquid from silicate magma. The parental magma of chromitites contains Al2O3 15.0wt%–16.5wt%, TiO20.30wt%–1.05wt% based on calculation with the composition of chromite, similar to parental magma of high‐Al chromitites from elsewhere and the estimated melt composition is comparable with that of MORB. Considering the high‐Mg olivine in disseminated chromitite and abundant hydrous inclusions, we propose that Kudi chromitites formed beneath a volcanic front during the subduction initiation of Proto‐Tethys.
Eclogites from the Guanshan and Yangkou areas of the Sulu orogen consist of garnet, omphacite, phengite, amphibole, quartz/coesite, rutile, and ilmenite. Garnet exhibits weak compositional zoning where Xgr decreases from the core to the mantle and then increases towards the rim, coupled with an increase in Xpy from the core to the mantle and then decrease towards the rim. Phase equilibria modelling with pseudosections calculated using THERMOCALC in the NCKFMASHTO system for the Guanshan and Yangkou eclogites records two stages of metamorphism: (I) prograde associated with quick subduction (Stage-I) and (II) retrograde associated with quick exhumation (Stage-II). Stage-I is recorded in the core-mantle zoning of garnet and Si content in phengite in the Guanshan and Yangkou eclogites with a mineral assemblage of Grt-Omp-Amp-Phg-Qtz-Rt ± Lws, and the P-T conditions are constrained at 22–26 kbar and 600–615 °C in Guanshan, while 24–26 kbar and 595–600 °C in Yangkou. The peak P-T conditions (Pmax = 33 kbar; T = 685 °C) of Guanshan eclogites are revealed by the maximum Si content in phengite and the minimum Xgr in the garnet mantle with the mineral assemblage of Grt-Omp-Phg-Coe-Rt ± Lws. The value of Pmax suggests that the subduction depth of the Guanshan eclogites exceeds 110 km. Stage-II is recorded in the mantle-rim zoning of garnet, and its P-T conditions are estimated to be 12–15 kbar and 780–820 °C for the Guanshan eclogites reflected by the assemblage of Grt-Omp-Amp-Pl-LL-Qtz-Rt ± ilm, and 13–14 kbar and 770–790 °C for the Yangkou eclogites by the assemblage of Grt-Omp-Amp-Pl-LL-Qtz-Rt. The two stages of metamorphism in the study areas are overall consistent with the regional metamorphic events, from ultra-high-pressure eclogite facies, through high pressure eclogite facies, to amphibole eclogite facies, with the ages of 245, 227 and 195 Ma, respectively.
The origin of ultramafic rocks, especially those in suture zones, has been a focus because they are not only important mantle sources of magma, but also provide substantial information on metamorphism and melt/fluid–peridotite interaction. Ultramafic rocks in Hujialin, in the central part of the Sulu orogen, include peridotite and pyroxenite. Although many papers on their origin and tectonic evolution have been published in the past few decades, these questions are still highly debated. Here, we present mineralogy, mineral composition, and bulk-rocks of these ultramafic rocks to evaluate their origin and tectonic evolution. The garnet clinopyroxenite is low in heavy rare-earth elements (HREE, 5.97–10.6 ppm) and has convex spoon-shaped chondrite-normalized REE patterns, suggesting the garnet formed later, and its precursor is clinopyroxenite. It is high in incompatible elements (i.e., Cs, Rb, Ba) and shows negative to positive U, Nb, and Ta anomalies, without pronounced positive Sr or Eu anomalies. Clinopyroxene in garnet clinopyroxenite contains high MgO (Mg# 0.90–0.97). The mineral chemistry and bulk-rock compositions are similar to those of reactive clinopyroxenite, suggesting that it originally formed via peridotite–melt interaction, and that such silicic and calcic melt might derive from the subducted Yangtze continent (YZC). Dunite contains olivine with high Fo (93.0–94.1), low NiO (0.11–0.29 wt.%) and MnO (≤0.1 wt.%), chromite with high Cr# (0.75–0.96), TiO2 (up to 0.88 wt.%), and Na2O (0.01–0.10 wt.%). It has negatively sloped chondrite-normalized REE patterns. Mineral chemistry and bulk rocks suggest dunite likely represent residual ancient lithosperic mantle peridotite beneath the North China Craton (NCC) that was overprinted by aqueous fluids. The lack of prograde and retrograde metamorphic minerals in dunite and irregular shaped mineral inclusions in chromite suggest dunite did not subduct to deep levels. Dunite mingled with garnet clinopyroxenite during exhumation of the latter at shallow depths. These ultramafic rocks, especially hydrated peridotite, may be important sources of Au for the Jiaodong gold province in the NCC.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.