Electrofluorochromic (EFC) materials have aroused great interest owing to their interesting ability of tuning fluorescence in response to the applied potential. However, some crucial characteristics, such as response speed, fluorescence contrast, and switching stability, are still not well realized to meet the requirements of practical applications. Herein, we designed and synthesized a novel polyamide-bearing aggregation-induced emission (AIE)-active tetraphenylethylene (TPE) and a highly conjugated triphenylamine (TPA) pendant group. The rational combination of the highly conjugated TPA and TPE caused the resultant polymer to exhibit highly integrated electrochromic (EC) and EFC performances including multiple color-changing (colorless to green to blue), fast response speed (1.8/1.1 s for EC and 0.4/2.9 s for EFC process), high fluorescence contrast (82 at the duration time of 20 s), and excellent long-term stability over 300 cycles. The strategy of AIE functionality by combing a highly conjugated redox unit demonstrates a synergistic effect to prepare high-performance emission/color dual-switchable materials, greatly promoting their applications in sensors, smart windows, and displays.
As a new type of suspension bearing, Magnetic-Liquid Double Suspension Bearing (MLDSB) is mainly supported by electromagnetic suspension and supplemented by hydrostatic supporting. Its bearing capacity and stiffness can be greatly improved. Because of the small liquid film thickness (it is smaller 10 times than air gap), the eccentricity, crack, bending of the rotor, and the assembly error, it is easy to cause a clearance-rubbing fault between the rotor and stator. The coating can be worn and peeled, the operating stability can be reduced, and then it is one of the key problems of restricting the development and application of MLDSB. Therefore, the clearance-rubbing dynamic equation of 2-DOF system of MLDSB is established and converted into Taylor Series form and the nonlinear components are retained. Dimensionless treatment is carried out by dimensional normalization method. Finally, the rotor displacement response under different rotor eccentricity ratio and rotating speeds is numerically simulated. The studies show that the trajectory of the rotor is periodic elliptic without clearance-rubbing phenomenon when the eccentricity ratio is less than 0.2, while the rotor is greatly affected by the rotation speed and a variety of motions, such as single-period, quasi-period, double-period and chaos, are presented when greater than 0.3. Within the largest range of rotating speed and eccentricity ratio, the rotor presents the single-period trajectory, and then the number of Poincare mapping point is 1, without a clearance-rubbing fault. When the rotational speed is in the scope of (9, 13) krpm and the eccentricity ratio is in the scope of (0.27, 0.4), the number of Poincare mapping point is more than one, the maximum dimensionless rubbing force is −5.7, and then clearance-rubbing fault occurs. The research can provide a theoretical basis for the safe and stable operation of MLDSB.
Magnetic-liquid double suspension bearing (MLDSB) is a new type of suspension bearing with electromagnetic suspension as the main part and hydrostatic supporting as the auxiliary part. It can greatly improve the bearing capacity and stiffness of rotor bearing system and is suitable for medium speed, heavy load, and frequent starting occasions. The electromagnetic system adopts PD control, and hydrostatic system adopts constant pressure supply model to adjust and control the rotor’s displacement in real time. Once bearing electromagnetic system fails, the “dropping-collision” phenomenon of the rotor will be triggered in operation process, leading to cracking and shedding of magnetic sleeve plating and magnetic pole plating. Then the operational reliability and stability of MLDSB will be greatly reduced. So in this paper, Firstly, the drop impact-rubbing equation of the single DOF bearing system under four failure models (upper unit failure, lower unit failure, bilateral failure, and power amplifier failure) is established. Secondly, the paper simulates influence laws of different structure and operation parameters (plating/liquid film thickness and oil pocket pressure, bias current) on falling rotor impact-rubbings behavior. The results show that: (1) the degree of “dropping-collision” of the rotor under the four failure models is successively as follows: power amplifier failure > upper unit failure > bilateral failure > lower unit failure. (2) Due to the impact-rubbing damping effect of hydraulic oil, it plays a certain inhibitory and buffering role on the phenomenon of “drop-collision”. The degree and probability of “dropping-collision” of rotor can be effectively reduced by increasing the pressure of oil chamber appropriately. (3) The rotor drop impact-rubbing behavior obtained from the test is basically consistent with the theoretical simulation, and the correctness of the theoretical simulation can be effectively verified. The research provides a theoretical basis for fault prevention and diagnosis of MLDSB.
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