Efficient separation of photogenerated electrons and holes, and associated surface reactions, is a crucial aspect of efficient semiconductor photocatalytic systems employed for photocatalytic hydrogen production. A new CoO /TiO /Pt photocatalyst produced by template-assisted atomic layer deposition is reported for photocatalytic hydrogen production on Pt and CoO dual cocatalysts. Pt nanoclusters acting as electron collectors and active sites for the reduction reaction are deposited on the inner surface of porous TiO nanotubes, while CoO nanoclusters acting as hole collectors and active sites for oxidation reaction are deposited on the outer surface of porous TiO nanotubes. A CoO /TiO /Pt photocatalyst, comprising ultra-low concentrations of noble Pt (0.046 wt %) and CoO (0.019 wt %) deposited simultaneously with one atomic layer deposition cycle, achieves remarkably high photocatalytic efficiency (275.9 μmol h ), which is nearly five times as high as that of pristine TiO nanotubes (56.5 μmol h ). The highly dispersed Pt and CoO nanoclusters, porous structure of TiO nanotubes with large specific surface area, and the synergetic effect of the spatially separated Pt and CoO dual cocatalysts contribute to the excellent photocatalytic activity.

This paper suggests a behavioral definition of (subjective) ambiguity in an abstract setting where objects of choice are Savage‐style acts. Then axioms are described that deliver probabilistic sophistication of preference on the set of unambiguous acts. In particular, both the domain and the values of the decision‐maker's probability measure are derived from preference. It is argued that the noted result also provides a decision‐theoretic foundation for the Knightian distinction between risk and ambiguity.

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The engineering vision of relying on the "smart sky" for supporting air traffic and the "Internet above the clouds" for in-flight entertainment has become imperative for the future aircraft industry. Aeronautical ad hoc Networking (AANET) constitutes a compelling concept for providing broadband communications above clouds by extending the coverage of Air-to-Ground (A2G) networks to oceanic and remote airspace via autonomous and self-configured wireless networking amongst commercial passenger airplanes. The AANET concept may be viewed as a new member of the family of Mobile ad hoc Networks (MANETs) in action above the clouds. However, AANETs have more dynamic topologies, larger and more variable geographical network size, stricter security requirements and more hostile transmission conditions. These specific characteristics lead to more grave challenges in aircraft mobility modeling, aeronautical channel modeling and interference mitigation as well as in network scheduling and routing. This paper provides an overview of AANET solutions by characterizing the associated scenarios, requirements and challenges. Explicitly, the research addressing the key techniques of AANETs, such as their mobility models, network scheduling and routing, security and interference are reviewed. Furthermore, we also identify the remaining challenges associated with developing AANETs and present their prospective solutions as well as open issues. The design framework of AANETs and the key technical issues are investigated along with some recent research results. Furthermore, a range of performance metrics optimized in designing AANETs and a number of representative multi-objective optimization algorithms are outlined.

The synergistic nature of bicomponent catalysts remains a challenging issue, due to the difficulty in constructing well-defined catalytic systems. Here we study the origin of synergistic effects in CoOx-Pt catalysts for selective hydrogenation by designing a series of closely contacted CoOxPt/TiO2 and spatially separated CoOx/TiO2/Pt catalysts by atomic layer deposition (ALD). For CoOx/TiO2/Pt, CoOx and platinum are separated by the walls of titania nanotubes, and the CoOx-Pt intimacy can be precisely tuned. Like CoOxPt/TiO2, the CoOx/TiO2/Pt shows higher selectivity to cinnamyl alcohol than monometallic TiO2/Pt, indicating that the CoOx-Pt nanoscale intimacy almost has no influence on the selectivity. The enhanced selectivity is ascribed to the increased oxygen vacancy resulting from the promoted hydrogen spillover. Moreover, platinum-oxygen vacancy interfacial sites are identified as the active sites by selectively covering CoOx or platinum by ALD. Our study provides a guide for the understanding of synergistic nature in bicomponent and bifunctional catalysts.