Modification of silicon nitride nanopores under electron beam (e-beam) irradiation was investigated using a scanning electron microscope (SEM). Under e-beam irradiation, all pores with diameters ranging from 40to200nm undergo shrinkage, and the shrinkage rate increases with the rate of energy deposition. By using the selected-area scanning tool in the SEM, the silicon nitride nanopores can be selectively reshaped based on localized e-beam irradiation, with a characteristic dimension smaller than 10nm. A selected-area shaping technique was proposed to controllably shrink and shape the nanopores to a special structure.

A hybrid metal-dielectric nano-aperture antenna is proposed for surface-enhanced fluorescence applications. The nano-apertures that formed in the composite thin film consist of silicon and gold layers. These were numerically investigated in detail. The hybrid nano-aperture shows a more uniform field distribution within the apertures and a higher antenna quantum yield than pure gold nano-apertures. The spectral features of the hybrid nano-apertures are independent of the aperture size. This shows a high enhancement effect in the near-infrared region. The nano-apertures with a dielectric gap were then demonstrated theoretically for larger enhancement effects. The hybrid nano-aperture is fully adaptable to large-scale availability and reproducible fabrication. The hybrid antenna will improve the effectiveness of surface-enhanced fluorescence for applications, including sensitive biosensing and fluorescence analysis.

A highly stable 16π-electron antiaromatic system based on a monocationic tetrabenzocorrole Cu(ii) complex is reported.

A facile method for the quantitative preparation of silver dibenzo-fused corrole Ag-1 is described. In contrast to the saddle conformation resolved by single-crystal X-ray analysis for Ag-1, it adopts an unprecedented domed geometry, with up and down orientations, when adsorbed on an Ag(111) surface. Sharp Kondo resonances near Fermi level, both at the corrole ligand and the silver center were observed by cryogenic STM, with relatively high Kondo temperature (172 K), providing evidence for a non-innocent Ag II -corroleC 2À species. Further investigation validates that benzene ring fusion and moleculesubstrate interactions play pivotal roles in enhancing Ag(4d-(x 2 Ày 2 ))-corrole (p) orbital interactions, thereby stabilizing the open-shell singlet Ag II -corroleC 2À on Ag(111) surface. Moreover, this strategy used for constructing metal-free benzene-ring fused corrole ligand gives rise to inspiration of designing novel metal-corrole compound for multichannel molecular spintronics devices.