New experimental results are presented for the solubility of carbon dioxide in the ionic liquid 1-N-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF 6 ]) for temperatures from (293 to 393) K and pressures up to about 9.7 MPa. Solubility pressures are correlated by means of the extended Henry's law.
New experimental results for the solubility of carbon dioxide in solvent mixtures of methanol and water are presented (at solvent mixture methanol mole fractions of (5, 10, 25, 50, 75, 90, 95, and 100) %, at (313.75, 354.35, and 395.0) K, and total pressures up to about 10 MPa). The experimental work is to provide a database for the development of a thermodynamic model to describe the gas solubility in saltfree and salt-containing mixed solvents.
The solubility of carbon dioxide in aqueous solutions containing
acetic acid and in aqueous
solutions containing sodium hydroxide was measured in the temperature
range from 313 to
433 K and total pressures up to 10 MPa. The molalities of acetic
acid or sodium hydroxide in
the liquid phase were about 4 and 1 mol/kg, respectively.
Experimental results are reported
and compared to correlations and predictions.
New experimental results for the solubility of hydrogen sulfide in aqueous solutions of the single salts sodium sulfate, ammonium sulfate, sodium chloride, and ammonium chloride at temperatures from 313 to 393 K and total pressures up to 10 MPa are reported. As in the salt-free system, a secondshydrogen sulfide-richsliquid phase is observed at high hydrogen sulfide concentrations. A model to describe the phase equilibrium is presented. Calculations are compared to the new experimental data.
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