We demonstrated optical amplification at 650 nm in KMnF3:Yb3+,Er3+@KMnF3:Yb3+ nanoparticles doped polymer waveguides for the first time.

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Gain characteristics of polymer waveguide amplifiers based on NaYF4:Yb3+, Er3+ nanocrystals (NCs) at 0.54 µm wavelength were investigated through numerical simulations. NaYF4:18%Yb3+, 1 0%Er3+ NCs were doped into SU-8 2005 polymer matrix as the core of a polymer waveguide. The absorption spectrum and photoluminescence spectrum of the NCs were recorded and analyzed. The Judd-Ofelt parameters were achieved by means of Judd-Ofelt theory: Ω2 = 6.302 x 10(-20) cm2, Ω4 = 0.69 x 10(-20) cm2, Ω6 =7.572 x 10(-20) cm2. We simulated the gain characteristics of the waveguide amplifier at 0.54 µm wavelength by combining the atomic rate equations with power propaga- tion equations. The gain curves had the saturation effects. A maximum gain -4.3 dB for the 5 cm waveguide with the Er3+ concentration of ~7.5 x 1025 m-3 was obtained.