Heavy metal (HM) contamination and accumulation is a serious problem around the world due to the toxicity, abundant sources, non-biodegradable properties, and accumulative behaviour of HMs. The degree of soil HM contamination in China, especially in the Yangtze River Delta, is prominent. In this study, 1822 pairs of soil and crop samples at corresponding locations were collected from the southern Yangtze River Delta of China, and the contents of Ni, Cr, Zn, Cd, As, Cu, Hg, and Pb were measured. The single pollution index in soil (SPI) and Nemerow composite pollution index (NCPI) were used to assess the degree of HM pollution in soil, and the crop pollution index (CPI) was used to explore the degree of HM accumulation in crops. The bioaccumulation factor (BAF) was used to investigate the translocation of heavy metals in the soil-crop system. The health risks caused by HMs were calculated based on the model released by the U.S. Environmental Protection Agency. The SPIs of all elements were at the unpolluted level. The mean NCPI was at the alert level. The mean CPIs were in the following decreasing order: Ni (1.007) > Cr (0.483) > Zn (0.335) > Cd (0.314) > As (0.232) > Cu (0.187) > Hg (0.118) > Pb (0.105). Only the mean content of Ni in the crops exceeded the national standard value. The standard exceeding rates were used to represent the percentage of samples whose heavy metal content is higher than the corresponding national standard values. The standard exceeding rates of Cu, Hg, and Cd in soil were significantly higher than corresponding values in crops. Meanwhile, the standard exceeding rates of Ni, As, and Cr in crops were significantly higher than corresponding values in soil. The chronic daily intake (CDI) of children (13.8 × 10−3) was the largest among three age groups, followed by adults (6.998 × 10−4) and seniors (5.488 × 10−4). The bioaccumulation factors (BAFs) of all crops followed the order Cd (0.249) > Zn (0.133) > As (0.076) > Cu (0.064) > Ni (0.018) > Hg (0.011) > Cr (0.010) > Pb (0.001). Therefore, Cd was most easily absorbed by crops, and different crops had different capacities to absorb HMs. The hazard quotient (HQ) represents the potential non-carcinogenic risk for an individual HM and it is an estimation of daily exposure to the human population that is not likely to represent an appreciable risk of deleterious effects during a lifetime. All the HQs of the HMs for the different age groups were significantly less than the alert value of 1.0 and were at a safe level. This indicated that citizens in the study area face low potential non-carcinogenic risk caused by HMs. The total carcinogens risks (TCRs) for children, adults, and seniors were 5.24 × 10−5, 2.65 × 10−5, and 2.08 × 10−5, respectively, all of which were less than the guideline value but at the alert level. Ingestion was the main pathway of carcinogen risk to human health.

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Four R 1 R 2 Si(OMe) 2 type compounds were added as an external electron donor (De) in propylene polymerization with TiCl 4 /Di/MgCl 2 type supported Ziegler−Natta catalysts (Di = internal donor). Each polypropylene (PP) sample was fractionated into three parts (atactic, medium-isotactic and isotactic PP), and the number of active centers ([C*]/[Ti]) in each PP fraction was counted using 2-thiophenecarbonyl chloride as the quenching and tagging agent. The gradual decrease of [C*]/ [Ti] with De/Ti ratio is ascribed to competitive and reversible coordination of De on either central Ti of the active center or Mg adjacent to the central Ti. The former coordination leads to deactivation of C*, and the latter one leads to still living C*. The chain propagation rate constant (k p ) of the active centers producing atactic, medium-isotactic and isotactic PP change with De/ Ti in different ways. Only the k p of active centers producing isotactic PP was evidently increased by De. Enhancement in isotacticity of PP product is found to be a combined result of both deactivation of active centers by De and selective activation of the active centers that produce isotactic PP. Changing the alkyl groups of R 1 R 2 Si(OMe) 2 leads to an altered balance between the deactivation and activation effects of De.

Soil salinization is a global issue resulting in soil degradation, arable land loss and ecological environmental deterioration. Over the decades, multispectral and hyperspectral remote sensing have enabled efficient and cost-effective monitoring of salt-affected soils. However, the potential of hyperspectral sensors installed on an unmanned aerial vehicle (UAV) to estimate and map soil salinity has not been thoroughly explored. This study quantitatively characterized and estimated field-scale soil salinity using an electromagnetic induction (EMI) equipment and a hyperspectral camera installed on a UAV platform. In addition, 30 soil samples (0~20 cm) were collected in each field for the lab measurements of electrical conductivity. First, the apparent electrical conductivity (ECa) values measured by EMI were calibrated using the lab measured electrical conductivity derived from soil samples based on empirical line method. Second, the soil salinity was quantitatively estimated using the random forest (RF) regression method based on the reflectance factors of UAV hyperspectral images and satellite multispectral data. The performance of models was assessed by Lin’s concordance coefficient (CC), ratio of performance to deviation (RPD), and root mean square error (RMSE). Finally, the soil salinity of three study fields with different land cover were mapped. The results showed that bare land (field A) exhibited the most severe salinity, followed by dense vegetation area (field C) and sparse vegetation area (field B). The predictive models using UAV data outperformed those derived from GF-2 data with lower RMSE, higher CC and RPD values, and the most accurate UAV-derived model was developed using 62 hyperspectral bands of the image of the field A with the RMSE, CC, and RPD values of 1.40 dS m−1, 0.94, and 2.98, respectively. Our results indicated that UAV-borne hyperspectral imager is a useful tool for field-scale soil salinity monitoring and mapping. With the help of the EMI technique, quantitative estimation of surface soil salinity is critical to decision-making in arid land management and saline soil reclamation.

Rapid heavy metal soil surveys at large scale with high sampling density could not be conducted with traditional laboratory physical and chemical analyses because of the high cost, low efficiency and heavy workload involved. This study explored a rapid approach to assess heavy metals contamination in 301 farmland soils from Fuyang in Zhejiang Province, in the southern Yangtze River Delta, China, using portable proximal soil sensors. Portable X-ray fluorescence spectroscopy (PXRF) was used to determine soil heavy metals total concentrations while soil pH was predicted by portable visible-near infrared spectroscopy (PVNIR). Zn, Cu and Pb were successfully predicted by PXRF (R2 >0.90 and RPD >2.50) while As and Ni were predicted with less accuracy (R2 <0.75 and RPD <1.40). The pH values were well predicted by PVNIR. Classification of heavy metals contamination grades in farmland soils was conducted based on previous results; the Kappa coefficient was 0.87, which showed that the combination of PXRF and PVNIR was an effective and rapid method to determine the degree of pollution with soil heavy metals. This study provides a new approach to assess soil heavy metals pollution; this method will facilitate large-scale surveys of soil heavy metal pollution.