In this paper, fly ash samples were collected from a coal-fired power in Shanghai. A series of experiments, including unburned carbon testing, mercury content measurement, SEM analysis, specific surface area, average pore size and pore volume test, were conducted, and the adsorption ability of the fly ash on the flue gas mercury was also experimentally studied. It has shown that fly ash with particle size bigger than 100µm is with the highest adsorption efficiency, 67.83%, and that fly ash with particle size smaller than 25µm is with the smallest adsorption efficiency, 13.67%. The relative mechanism was analyzed.
The mercury concentration in the coals from Datong and Xiaoyi, Shanxi has been measured to study the relationship between mercury enrichment in coal and coalseam depth. Ten samples were researched, of which 7 coal and rock samples from the main coalseam and the places around it were collected at a miner in Datong city, and 3 coal samples from three coalseams at a miner in Xiaoyi city. The mercury concentration in the coal and rock samples was measured with US EPA Method7471, which is a standard method recommended by the US EPA. The results show that the mercury enrichment in coal is higher than that in rock in the same conditions, and the mercury concentration in the longer-buried coal is higher than that of the shorter-buried. However, the mercury concentration in coal with depth has no definite linear correlation, varying in different coal fields.
In this paper, magnetic beads were separated from two different power plants fly ash by magnetic separation, and the separated magnetic beads were analyzed by XRD. In a self-built fixed-bed system, the experiments that magnetic beads from two power plants, α-Fe2O3 and γ-Fe2O3 affect formation distribution of mercury in flue gas were carried out. The results showed that the magnetic beads in fly ash have a certain capacity to oxidize the mercury in flue gas, and the γ-Fe2O3 has greater influence on the species distribution of mercury than α- Fe2O3.
This paper analyses and studies control of nitrogen on Al- killed steel using the methods of production experiment in the flow of molten iron pretreatment - 180t converter - LF refining – continuous caster. Results show that adding aluminum final deoxidization should be divided into two steps: Firstly, putting some aluminum into molten steel after adding alloy in the process of tapping of molten steel, making the [O] reduce to 6 ~ 7ppm. Secondly, adding aluminum wire in LF-refining making [O] and [N] reach the required values. LF-refining should try to shorten operating time and original mission ought to be finished ahead. Desulfurization should be completed in the flow of molten iron pretreatment and the tapping of molten steel. Process of removal inclusions should be accomplished by adding slag during tapping of molten steel and blowing-mixing. LF-refining has scarcely any slagging task, it only needs to complete adjustment ingredient task. Alloy and carburant which contains extremely low nitrogen should be choosed, so that nitrogen in molten steel can be steadily controled below 30ppm.
Through chemical composition analysis of corroded steel sample and enamel steel sample, through SEM-EDS and XRD analysis of corroded steel sample, the corrosion characteristics was studied, the possible influence to the heat exchange and flow rate were also analyzed. Through polarization curves experiment, a comparative analysis of the corrosion resistance between old GGH materials and newly installed enamel steel is made. The results have shown that the corrosion resistance with the heat transfer surface in GGH will decrease with the temperature increasing, but the enamel steel’s corrosion resistance and stability is strikingly better than the old materials.
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