Recently, there has been great interest in flexible and wearable energy devices for applications in flexible and stretchable electronics. Even though future developments are moving toward thinner, lighter, and cheaper solutions, [1,2] many existing energy-harvesting and storage devices are still too bulky and heavy for intended applications. For example, high-efficiency dye-sensitized solar cells (DSSCs) employ fluorine-doped tin oxide (FTO) glass as the substrate of working electrode. However, the use of rigid FTO glass has restricted adaptability of DSSCs during transportation, installation, and application, [2] requiring further development of flexible cells to improve DSSC adaptability. To develop flexible and wearable electronics, not only new materials for the substrates used in energy storage devices such as batteries and supercapacitors need to be explored, but future development of higher performance energy systems still depends on the employment of new and lighter electrode materials.In recent years, electrochemical supercapacitors have attracted much attention as novel energy-storage devices because of their high power density, long life cycles, and high efficiency. [3][4][5][6][7][8][9][10][11][12] Supercapacitors can deliver higher power than batteries and store more energy than conventional capacitors. [13,14] Current research on supercapacitors has focused on their applications in electric vehicles, hybrid electric vehicles, and backup energy sources. Thus, conventional supercapacitors are heavy and bulky, and it is still a challenge to achieve high efficiency miniaturized energy-storage devices that are compatible with the flexible/wearable electronics. [15] Herein, we present a prototype of a high-efficiency fiberbased electrochemical microsupercapacitor using ZnO nanowires (NWs) as electrodes. These fiber supercapacitors, which have great potential for scale-up, comprise two electrodes that employ a flexible plastic wire and a Kevlar fiber as a substrate. Both wire and fiber are covered with arrays of highquality ZnO NWs grown by the hydrothermal method, and ZnO NWs on a Kevlar fiber was coated with a thin gold film to improve the charge-collection capacity. Furthermore, employment of ZnO NWs could provide exciting solutions to the future development of wearable energy devices. Our fiber-based microsupercapacitor would be large enough to be used in self-powering nanosystems, such as a power shirt using piezoelectric ZnO NWs grown radially around textile fibers.Even though conventional research efforts on bulky supercapacitors have focused on the use of carbon-based materials, such as activated carbons, and some transition metal oxides, such as RuO 2 and ZnO, could have several advantages over the conventional electrode materials of supercapacitors for the wearable electronics. First, it can be grown at low temperatures (less than 100 8C) by a chemical approach on any substrate and any shape substrate. Second, it is biocompatible and environmentally friendly material. Furthermore, ZnO NWs [16][17...