A Fe-based amorphous composite coating was deposited on a carbon steel substrate by arc spraying, and remelted with different laser energies by the Nd: YAG laser cladding system, in order to improve the mechanical properties of the coatings. The microstructure and microhardness of the composite coatings were investigated. The variation of harndness was measured as a function of the modified layer depth, which indicates that the laser remelting improves the bonding strength and hardness. Increasing the laser power, the quality of coating gets better, but the amorphous volume fraction decreases. It is obtained that the optimal laser electric current for the coating of 280 μm thickness is about 300 A, in which the remelted coating with medium energy densities has the highest average Vickers hardness of 741. Through the volume fraction change of the nanocrytals, the hardness of the composite coating is regulated by the laser power input, which amplified the application fields of the amorphous coatings.

The microstructure and corrosion resistance of Fe-based amorphous coatings prepared by laser remelting after arc spraying were studied. The laser remelting process was carried out under different energy inputs, and the processing parameters varied with the different currents, pulse widths and scanning speeds. The corrosion behavior of the coatings in 1 mol/L NaCl solution was studied through potentiodynamic and potentiostatic polarization test. The morphology and microstructure of the coatings were characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM), and electrochemical analyzer. A Vickers hardness tester was also used to measure the microhardness of the coatings. The analysis of the microstructure shows that the amorphous coatings are composed of amorphous matrix and nanocrystalline phases. The diffusion of elements indicates a metallurgical bonding between the coating and substrate. The electrochemical corrosion results obtained from the Tafel polarization curves verify that the amorphous composite coatings prepared by different methods show no significant differences in their corrosion resistance, while the microhardness of laser remelting coatings increase obviously with the increase of laser currents. The corrosion resistance of laser remelting coatings is improved extensively due to the amorphous matrix and embedded nanocrystals, which popularizes the applications of amorphous coatings to a large extent.