A hybrid magnetic metal–organic framework HKUST-1 synthesized via chemical bonding approach possesses efficient and recyclable adsorption performance for Congo red.

We describe a facile method for the preparation of magnetic microparticles consisting of a metal-organic framew o r k ( M O F ) o f C u ( I I ) -B T C ( B T C = 1 , 3 , 5 -benzenetricarboxylate) for rapid magnetic solid-phase extraction (MSPE) of the dye Congo Red (CR) from aqueous solution. Magnetization of the MOF and solid-phase extraction of CR was simultaneously accomplished by mixing, under ultrasonication, the MOF and silica-coated magnetite microparticles in the solution to be extracted. Under optimized conditions, the magnetic MOF hybrid exhibits a fast adsorption rate and a high removal efficiency (>97 %) toward CR even over 15-fold reuse, which also features high adsorption capacity of 97.7 and 92.5 % for cationinc Methylene Blue (MB) and Crystal Violet (CV), respectively. The desorption of CR from the magnetic MOF was realized by washing it with ethanol and water. The material is considered to be a promising new adsorbent for use in wastewater treatment and in analytical preconcentration.

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Core-shell metal-organic framework materials have attracted considerable attention mainly due to their enhanced or new physicochemical properties compared with their single-component counterparts. In this work, a core-shell heterostructure of CoFe2 O4 -Zeolitic Imidazolate Framework-8 (ZIF-8@CoFe2 O4 ) is successfully fabricated and used as an solid-phase extraction adsorbent to efficiently extract Congo Red and Basic Red 2 dyes from contaminated aqueous solution. Vibrating sample magnetometry indicates that the saturated magnetization of ZIF-8@CoFe2 O4 is 3.3 emu/g, which is large enough for magnetic separation. The obtained hybrid magnetic metal-organic framework based material ZIF-8@CoFe2 O4 can remove the investigated dyes very fast within 1 min of the contact time. The adsorbent ZIF-8@CoFe2 O4 also shows a good reusability. After regeneration, the adsorbent can still exhibit high removal efficiency (∼97%) toward Congo Red for five cycles of desorption-adsorption. This work reveals the great potential of core-shell ZIF-8@CoFe2 O4 sorbents for the fast separation and preconcentration of organic pollutants in aqueous solution before high-performance liquid chromatography analysis.

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