Polylactic acid (PLA) was reinforced with ultralong cellulose and chitin nanofibers extracted from four raw materials by extrusion. The mechanical, rheological, thermal, and viscoelastic performances of four nanocomposites were comparatively studied in detail. The results showed that fibrillation of poplar was much easier than that of cotton, and fibrillation of crab shell was relatively hard as compared to prawn shell. The poplar CNFs/PLA composite exhibited the best mechanical properties among four nanocomposites due to the highest aspect ratio of nanofibers, while both the cotton CNFs/PLA composite and the crab shell CHNFs/PLA composite had low mechanical strength due to the relatively low aspect ratio. FE-SEM images showed that the ultralong nanofibers were uniformly dispersed in PLA matrix for all four samples with the water preblending method. The CTE values of the nanocomposites with 40 wt% nanofibers extracted from poplar, cotton, crab shell, and prawn shell were 69.5 × 10−6 K−1, 79.6 × 10−6 K−1, 77.2 × 10−6 K−1, and 75.3 × 10−6 K−1, respectively. All the results indicated that the aspect ratio of the nanofibers has a great influence on the performance of the composites, irrespective of the composites prepared by cellulose or chitin.

No abstract

Ionomer can be used as an ideal compatibilizer to improve simultaneously both the flowability and the mechanical properties of cellulose nanofibers/PLA composite.

In order to develop a bio-based epoxy resin with high mechanical and thermal performance, cork particles and nanocellulose were introduced into the rosin-based epoxy resin to improve the toughness, stiffness and thermal stability. The flexural properties of the epoxy composites indicated that the strength and modulus were reduced when the content of cork particles was relatively high (>3%) due to the low stiffness and modulus of cork itself. However, the flexural performance was significantly improved after the addition of 1% nanocellulose. In contrast to the flexural properties, the impact toughness results showed the synergistic toughening effects of nanocellulose and cork particles on the rosin-based epoxy resin. The highest impact toughness of 13.35 KJ/m2 was found in the epoxy composite with 1% cellulose nanofibers and 3% cork particles, an increase of 149.07% compared to the neat epoxy. Cork particle size also had a significant effect on the mechanical properties of the composites. Both the flexural and impact results showed first a rise and then a fall with a decrease in the cork size. TGA results indicated cork particles and nanocellulose could have a synergistic enhancing effect on the thermal stability of the rosin-based epoxy resin. This work can add value to rosin and cork waste and widen the industrial applications of the epoxy resin.