Laboratory experiments were conducted on the erosion-corrosion resistance of four groups of austenitic cast iron with different nickel contents under different acidic slurry conditions. The experiments involved measuring weight loss, examining corrosion morphology as well as X-ray diffraction analysis and electrochemical techniques. While the results showed little erosioncorrosion in a base sand particles environment, erosion-corrosion increased progressively with additions of HCl solution. With the presence of H z , intergranular corrosion and pitting attacks were centred at the boundaries of graphite flakes and alloy carbides. The electrochemical tests showed that the enrichment of nickel and copper in low Ni austenite cast iron can increase the corrosion potential to some extent. As a result, the low Ni cast iron in which Ni content is 8?36 wt-%, and Mn content is 6?57 wt-% exhibited better corrosion resistance than other low Ni cast irons and demonstrated comparable performance with high Ni austenite cast iron.
The
low ionic conductivity and mechanical strength are important
factors impeding the application of solid polymer electrolytes. Herein,
we design synthesize an organic/inorganic hybrid star-shaped polymer
of octa(poly(methyl methacrylate)–poly(poly(ethylene glycol)
methyl ether methacrylate) cage oligomeric silsesquioxanes (POSS–(PMMA–PPEGMEM)8) by one-step free atom transfer radical polymerization (ATRP),
and compound with Li6.4La3Zr1.4Ta0.6O12 (LLZTO) to prepare a composite polymer electrolyte
membrane (LP-CPEM). The star-shaped structure of the POSS–(PMMA–PPEGMEM)8 induced by octachloropropyl polyhedral cage oligomeric silsesquioxane
(OCP-POSS) is beneficial to reduce the crystallinity of polymer and
increase the movement of the polymer chain to form a continuous interconnected
ion migration channel. The LLZTO fillers in the LP-CPEM could simultaneously
hinder the orderly arrangement of polymer chains and provide other
ion transport paths to increase the ion conductivity of LP-CPEM. The
LP-CPEM with 7.5 wt % LLZTO has higher ionic conductivity of 3.8 ×
10–4 S cm–1 at 30 °C and
high mechanical strength (5.2 MPa). Additionally, Li/Li symmetric
cells demonstrate stable constant current charging/discharging during
1000 h at 0.1 mA cm–2, and the all-solid-state batteries
fabricated by the LP-CPEM exhibit good cyclic stability. It is promising
for the development of next-generation high-safety all-solid-state
lithium metal batteries.
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