A new one-step procedure is described for the synthesis of disubstituted imidazolium chlorides. 1,3-Dialkoxymethylimidazolium chlorides thus obtained can be employed as synthetic precursors of symmetrical ILs. The salts have been found to exhibit antimicrobial activity and an antielectrostatic effect. Their densities and viscosities have been determined and are reported herein. It has also been demonstrated that the ILs can be decomposed using an aqueous solution of KMnO(4). For each IL, the permanganate index (I(Mn)) has been estimated, which varies with the structure of cation. The only limitation of I(Mn) is the degree to which the IL dissolves in water.
In this study ionic liquids (3-alkoxymethyl-1-methylimidazolium tetrafluoroborates and hexafluoro-phosphates) are successfully used for wood preservation. These liquids are new biocides as well as new solvents which penetrate wood well. The prepared ionic liquids with an alkoxymethyl substituent, which consisted of 7, 8 or 9 carbon atoms, exhibited fungicidal activity against Coniophora puteana (Schum.: Fr.) Karst., Trametes versicolor (L.: Fr.) Pilá t and Sclerophoma pityophila (Corda) v. Hö hn. The effective and lethal doses were measured by the agar-plate method. In their activity against wood degrading fungi, ionic liquids such as 1-methyl-3-octyloxymethylimidazolium and 1-methyl-3-nonyloxymethylimidazolium tetrafluoroborates were comparable with commercially available benzalkonium chloride and didecyldimethylammonium chloride. Ionic liquids both with and without DDAC penetrated into Scots pine wood very well.
This study evaluated the effect of adding a new step, termed conditioning, to the traditional processing of leaves from Morus alba var. zolwinska wielkolistna grown in Poland (WML-P). This step, modeled on tea leaves processing, was conducted in a controlled environment on a semi-technical scale. The primary goal was to evaluate the effect of the WML-P conditioning for 1–4 h at 32–35 °C on the content of bioactive compounds (total phenolics, phenolic acids, flavonols, 1-deoxynojirimycin) and antioxidant activity (radical scavenging against DPPH, antioxidant capacity, chelating activity and ferric reducing antioxidant potential) of the lyophilized extracts. For the first time WML-P extracts content was comprehensively characterized by assessing dietary fiber fractions, fatty acids, amino acids, macro- and microelements and chlorophyll content. Compared to the traditional process, adding the conditioning step to WML-P processing resulted in an increased total phenolics content, radical scavenging capacity, ability to quench 2,2-diphenyl-1-picrylhydrazyl (DPPH•) and iron-chelating ability in the lyophilized extracts. The beneficial effect depended on conditioning time. The highest flavonols and phenolic acids content were found after 2-h conditioning. We concluded that adding a 2-h conditioning step to traditional WML-P processing results in getting WML-P lyophilized extract with increased bioactive compounds content and high antioxidant activity.
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