In this paper, we study the plastic relaxation of InGaN layers deposited on (0001) GaN bulk substrates and (0001) GaN/sapphire templates by molecular beam epitaxy. We demonstrate that the InGaN layers relax by the formation of (a+c)-type misfit dislocations gliding on pyramidal planes in the slip system ⟨112¯3⟩{112¯2} down to the interface where they form a trigonal dislocation network. Combining diffraction contrast and large angle convergent beam electron diffraction analyses performed using a transmission electron microscope, we reveal that all (a+c)-type dislocations belonging to one subset of the network exhibit Burgers vectors with the same c-component. This relaxation mechanism leads to partially relaxed InGaN layers with smooth surfaces and threading dislocation densities below 109 cm−2. Such layers are of potential interest as pseudo-substrates for the growth of InGaN heterostructures.
III-nitride compound semiconductors are breakthrough materials regarding device applications. However, their heterostructures suffer from very high threading dislocation (TD) densities that impair several aspects of their performance. The physical mechanisms leading to TD nucleation in these materials are still not fully elucidated. An overlooked but apparently important mechanism is their heterogeneous nucleation on domains of basal stacking faults (BSFs). Based on experimental observations by transmission electron microscopy, we present a concise model of this phenomenon occurring in III-nitride alloy heterostructures. Such domains comprise overlapping intrinsic I1 BSFs with parallel translation vectors. Overlapping of two BSFs annihilates most of the local elastic strain of their delimiting partial dislocations. What remains combines to yield partial dislocations that are always of screw character. As a result, TD nucleation becomes geometrically necessary, as well as energetically favorable, due to the coexistence of crystallographically equivalent prismatic facets surrounding the BSF domain. The presented model explains all observed BSF domain morphologies, and constitutes a physical mechanism that provides insight regarding dislocation nucleation in wurtzite-structured alloy epilayers.
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