Abstract. The coarse grid spacing of global circulation models necessitates the application of downscaling techniques to investigate the local impact of a changing global climate. Difficulties arise for data-sparse regions in complex topography, as they are computationally demanding for dynamic downscaling and often not suitable for statistical downscaling due to the lack of high-quality observational data. The Intermediate Complexity Atmospheric Research (ICAR) model is a physics-based model that can be applied without relying on measurements for training and is computationally more efficient than dynamic downscaling models. This study presents the first in-depth evaluation of multiyear precipitation time series generated with ICAR on a 4×4 km2 grid for the South Island of New Zealand for an 11-year period, ranging from 2007 to 2017. It focuses on complex topography and evaluates ICAR at 16 weather stations, 11 of which are situated in the Southern Alps between 700 and 2150mm.s.l (m m.s.l refers to meters above mean sea level). ICAR is assessed with standard skill scores, and the effect of model top elevation, topography, season, atmospheric background state and synoptic weather patterns on these scores are investigated. The results show a strong dependence of ICAR skill on the choice of the model top elevation, with the highest scores obtained for 4 km above topography. Furthermore, ICAR is found to provide added value over its ERA-Interim reanalysis forcing data set for alpine weather stations, improving the median of mean squared errors (MSEs) by 30 % and up to 53 %. It performs similarly during all seasons with a MSE minimum during winter, while flow linearity and atmospheric stability are found to increase skill scores. ICAR scores are highest during weather patterns associated with flow perpendicular to the Southern Alps and lowest for flow parallel to the alpine range. While measured precipitation is underestimated by ICAR, these results show the skill of ICAR in a real-world application, and may be improved upon by further observational calibration or bias correction techniques. Based on these findings ICAR shows the potential to generate downscaled fields for long-term impact studies in data-sparse regions with complex topography.

In vehicles that are parked, no ventilation and/or air conditioning takes place. If a vehicle is exposed to direct solar radiation, an immediate temperature rise occurs. The high cabin air temperature can threaten children and animals that are left unattended in vehicles. In the USA, lethal heat strokes cause a mean death rate of 37 children per year. In addition, temperature-sensitive goods (e.g. drugs in ambulances and veterinary vehicles) can be adversely affected by high temperatures. To calculate the rise of the cabin air temperature, a dynamic model was developed that is driven by only three parameters, available at standard meteorological stations: air temperature, global radiation and wind velocity. The transition from the initial temperature to the constant equilibrium temperature depends strongly on the configuration of the vehicle, more specifically on insulation, window area and transmission of the glass, as well as on the meteorological conditions. The comparison of the model with empirical data showed good agreement. The model output can be applied to assess the heat load of children and animals as well as temperature-sensitive goods, which are transported and/or stored in a vehicle.

Laser-induced acoustic desorption (LIAD) has recently been established as a tool for analytical chemistry. It is capable of launching intact, neutral, or low charged molecules into a high vacuum environment. This makes it ideally suited to mass spectrometry. LIAD can be used with fragile biomolecules and very massive compounds alike. Here, we apply LIAD time-of-flight mass spectrometry (TOF-MS) to the natural biochromophores chlorophyll, hemin, bilirubin, and biliverdin and to high mass fluoroalkyl-functionalized porphyrins. We characterize the variation in the molecular fragmentation patterns as a function of the desorption and the VUV postionization laser intensity. We find that LIAD can produce molecular beams an order of magnitude slower than matrix-assisted laser desorption (MALD), although this depends on the substrate material. Using titanium foils we observe a most probable velocity of 20 m/s for functionalized molecules with a mass m = 10 000 Da.