Abstract. We present an aerosol size distribution model summarizing measurements of sulfate, sea salt, and dust aerosol obtained in the marine boundary layer and marine free troposphere. Stratospheric aerosol cases are not included here. Aerosols were sampled in both both clean background conditions and aged anthropogenic aerosol (>3 days) which had advected over the ocean. Model size distributions are developed for the sulfate accumulation mode, sea-salt coarse mode, and dust coarse mode. The data demonstrate that both the accumulation and coarse mode aerosol gradually shift to larger diameters as the aerosol mass increases. Based on this relationship, it is possible to estimate the size distribution based on aerosol mass. Comparisons with other aerosol models show significant differences, which suggest further measuring and modeling efforts are needed.
Experiment (UAE 2 ) was conducted in the southern Arabian Gulf region. We present atmospheric thermodynamic and aerosol data collected on 18 flights by the South African Aerocommander aircraft. In the first few kilometers, we observed high concentrations of both regional dust (from 100 to 300 mg m À3 in background, to over 1.5 mg m À3 in events) and ubiquitous sulfate based pollution from the Gulf's prevalent petroleum industry (10-100 mg m À3 ). Smoke and pollution from Europe and possibly Africa were found at levels between 1.5 and 5 km. Inland, classic deep over desert boundary layer characteristics were found. Over the Arabian Gulf, dust and pollution were most often either trapped below or sequestered above a strong stable boundary. However, there were cases where a well-distributed aerosol layer crossed the inversion uniformly. Data suggest that the observed vertical profiles can be explained by the rapid formation of stable marine boundary layers as air moves offshore. This can decouple aerosol layers from within the boundary layer to those aloft in regions of vertical wind shear. In the case of pollution, the ability of flaring plumes to penetrate the inversion may also in part determine layering. In coastal regions without vertical wind shear, uniform concentrations with height across the inversion are a result of internal boundary layer development. We conclude that the bulk of the observed variability in particle vertical distribution appear to be controlled by mesoscale and microscale processes, such as the sea/land breeze.
The capability to analyze and detect the composition of distant samples (minerals, organics, and chemicals) in real time is of interest for various fields including detecting explosives, geological surveying, and pollution mapping. For the past 10 years, the University of Hawaii has been developing standoff Raman systems suitable for measuring Raman spectra of various chemicals in daytime or nighttime. In this article we present standoff Raman spectra of various minerals and chemicals obtained from a distance of 120 m using single laser pulse excitation during daytime. The standoff Raman system utilizes an 8-inch Meade telescope as collection optics and a frequency-doubled 532 nm Nd : YAG laser with pulse energy of 100 mJ/pulse and pulse width of 10 ns. A gated intensified charge-coupled device (ICCD) detector is used to measure time-resolved Raman spectra in daytime with detection time of 100 ns. A gate delay of 800 ns (equivalent to target placed at 120 m distance) was used to minimize interference from the atmospheric gases along the laser beam path and near-field scattering. Reproducible, good quality single-shot Raman spectra of various inorganic and organic chemicals and minerals such as ammonium nitrate, potassium perchlorate, sulfur, gypsum, calcite, benzene, nitrobenzene, etc., were obtained through sealed glass vials during daytime. The data indicate that various chemicals could easily be identified from their Raman fingerprint spectra from a far standoff distance in real time using single-shot laser excitation.
Aerosol optical depths and lidar measurements were obtained under the plume of Hawaii Kilauea Volcano on August 17, 2001, ∼9 km downwind from the erupting Pu'u O'o vent. Measured aerosol optical depths (at 500 nm) were between 0.2–0.4. Aerosol size distributions inverted from the spectral sun photometer measurements suggest the volcanic aerosol is present in the accumulation mode (0.1–0.5 micron diameter), which is consistent with past in situ optical counter measurements. The aerosol dry mass flux rate was calculated to be 53 Mg d−1. The estimated SO2 emission rate during the aerosol measurements was ∼1450 Mg d−1. Assuming the sulfur emissions at Pu'u O'o vent are mainly SO2 (not aerosol), this corresponds to a SO2 half‐life of 6.0 hours in the atmosphere.
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