The mechanical properties of ceramic foams obtained through a novel process that uses the direct foaming and pyrolysis of preceramic polymer/polyurethane solutions were investigated. The elastic modulus, flexural strength, and compressive strengths were obtained for foams in the as-pyrolyzed condition; values up to 7.1 GPa, 13 MPa, and 11 MPa, respectively, were obtained. The strength of the foam was virtually unchanged at temperatures up to 1200°C in air; however, long-term exposure at 1200°C led to a moderate degradation in strength, which was attributed to the evolution of intrastrut porosity during the oxidation of residual free carbon, as well as devitrification of the foams struts.
In this study, the elastic constants of a titanium diboride (TiB2) single crystal were measured using resonant ultrasound spectroscopy. In contrast to previous work, the current results are consistent with the measured elastic constants of TiB2 polycrystals. In addition, the crystal anisotropy of TiB2 was examined. The current data show that the elastic properties of TiB2 are much more isotropic than previously considered.
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