Voltammetric detection is a potentially powerful method of detection for high performance liquid chromatography and flow injection analysis. A problem that needs a solution is its inferior detection limit compared to that obtained with ampcrometric detection. The shape of the potential waveform has been investigated in the search for methods of improving the detection limit of voltammetric detection. As a result, large amplitude sine wave potential perturbations have been found to give improved signal-tonoise ratios when compared to the values found for a corresponding triangle waveform (by a factor of from 1.1 to 5). This is principally due to the fact that the background current from a large amplitude triangle perturbation is spread over a wider frequency region. Signal processing techniques such as digital filtering have also been investigated. Digital bandpass filtering can be used to improve the signal to noise ratio by a factor of 2-13. Qualitative information (e.g., half-wave potential) is obtained through observing the phase angle at harmonics of the fundamental frequency.
Recently a sound absorption study was undertaken involving a wide range of samples of common automotive materials from ten different manufacturers. The study included 128 porous absorbers of varying thicknesses and material types (cotton blends, microfibers, etc.). This paper presents the results of that study. It was found that no single material outperformed all the others; rather, metrics such as specific air flow resistance were more important than the specific material making up the absorber. In general, samples within a certain range of thickness and specific air flow resistance showed the best performance. However, there was no single value of specific flow resistance that was optimal for all material thicknesses. Instead thinner materials required higher flow resistivity than thicker materials. In addition, because the specific air flow resistance is such an important parameter, the presence or lack of a scrim had a significant impact on absorption results.
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