beyond doubt.2 Although there is good evidence1-3 that the pyrolysis of an amine oxide involves synelimination, this mechanism has never been rigorously tested by deuterium-labeling experiments.
Pyrolysis of the imino-ether V derived from benzanilimino chloride and methyl o-hydroxyphenylacetate gave, in additionThe structure of this abnormal product to the expected Chapman product, 3-benzanilimino-2(3H)-benzofuranone (XVI). was deduced from hydrolyses and proved by synthesis.(18) R. StollC, Chem. Bcr., 47, 2120 (1914).
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