No abstract

Mechanosynthesis as a Simple Method to Obtain a Magnetic Composite (Activated Carbon/Fe 3 O 4) for Hyperthermia Treatment.

Biochar is a carbonaceous and porous material with limited adsorption capacity, which increases by modifying its surface. Many of the biochars modified with magnetic nanoparticles reported previously were obtained in two steps: first, the biomass was pyrolyzed, and then the modification was performed. In this research, a biochar with Fe3O4 particles was obtained during the pyrolysis process. Corn cob residues were used to obtain the biochar (i.e., BCM) and the magnetic one (i.e., BCMFe). The BCMFe biochar was synthesized by a chemical coprecipitation technique prior to the pyrolysis process. The biochars obtained were characterized to determine their physicochemical, surface, and structural properties. The characterization revealed a porous surface with a 1013.52 m2/g area for BCM and 903.67 m2/g for BCMFe. The pores were uniformly distributed, as observed in SEM images. BCMFe showed Fe3O4 particles on the surface with a spherical shape and a uniform distribution. According to FTIR analysis, the functional groups formed on the surface were aliphatic and carbonyl functional groups. Ash content in the biochar was 4.0% in BCM and 8.0% in BCMFe; the difference corresponded to the presence of inorganic elements. The TGA showed that BCM lost 93.8 wt% while BCMFe was more thermally stable due to the inorganic species on the biochar surface, with a weight loss of 78.6%. Both biochars were tested as adsorbent materials for methylene blue. BCM and BCMFe obtained a maximum adsorption capacity (qm) of 23.17 mg/g and 39.66 mg/g, respectively. The obtained biochars are promising materials for the efficient removal of organic pollutants.

Los carbones activados (CA) son de gran interés debido a las excepcionales propiedades físicas y químicas que poseen, estos materiales se presentan en forma de gránulos o polvos, pero recientemente se ha comercializado una nueva forma de CA conocida como Fibra de Carbón Activado (FCA), que se puede fabricar en dos presentaciones, como tela y como fieltro. Las Telas de carbón activado (TCA) son materiales que poseen excelentes propiedades que las hacen superiores en comparación con las formas tradicionales y se producen a partir de precursores, mediante diversos procesos que incluyen activación física o química, entre los agentes impregnantes más utilizados se encuentran el KOH, H3PO4, ZnCl2, AlCl3, NH4Cl, Na2CO3 y K2CO3, cuya función principal es servir como deshidratantes impidiendo al mismo tiempo la producción de alquitranes. Las características y propiedades que adquieren las TCA dependen de la naturaleza del material que se utilizó para producirlas, estas características han sido aprovechadas en una gran cantidad de aplicaciones, como: medicina, sistemas de soporte de catalizadores, en la industria para la adsorción de contaminantes, purificación de aguas y tratamiento de aguas residuales, entre otras. Esta revisión muestra las generalidades y aplicaciones en estudios recientes y resume las aplicaciones de las TCA de las diferentes investigaciones realizadas, así como su proceso de obtención.

No abstract