The purposes of this study were 1) to analyse the different pacing behaviours based on athlete's performance and 2) to determine whether significant differences in each race split and the runner's performance implied different race profiles. A total of 2295 runners, which took part in Berlin's marathon (2017), met the inclusion criteria. 4 different groups were created based on sex and performance.

Seven aromatic polyamides and copolyamides were synthesized from two different aromatic diamines: 4,4′-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline (HFDA) and 2,4-Aminobenzenesulfonic acid (DABS). The synthesis was carried out by polycondensation using isophthaloyl dichloride (1SO). The effect of an increasing molar concentration of the sulfonated groups, from DABS, in the copolymer properties was evaluated. Inherent viscosity tests were carried out to estimate molecular weights. Mechanical tests were carried out under tension, maximum strength ( σ max), Young’s modulus (E), and elongation at break (εmax) to determine their mechanical properties. Tests for water sorption and ion exchange capacity (IEC) were carried out. Proton conductivity was measured using electrochemical impedance spectroscopy (EIS). The results indicate that as the degree of sulfonation increase, the greater the proton conductivity. The results obtained showed conductivity values lower than the commercial membrane Nafion 115 of 0.0065 S cm−1. The membrane from copolyamide HFDA/DABS/1S0-70/30 with 30 mol DABS obtained the best IEC, with a value of 0.747 mmol g−1 that resulted in a conductivity of 2.7018 × 10−4 S cm−1, lower than the data reported for the commercial membrane Nafion 115. According to the results obtained, we can suggest that further developments increasing IEC will render membranes based on aromatic polyamides that are suitable for their use in PEM fuel cells.

The objectives this study were to examine the integrated use of oil–coagulant for the direct extraction of coagulant from Moringa oleifera (MO) with 5% and 10% (NH4)2SO4 extractor solution to harvest Scenedesmus obliquus cultivated in urban wastewater and to analyze the oil extracted from MO and S. obliquus. An average content of 0.47 g of coagulant and 0.5 g of oil per gram of MO was obtained. Highly efficient algal harvest, 80.33% and 72.13%, was achieved at a dose of 0.38 g L−1 and pH 8–9 for 5% and 10% extractor solutions, respectively. For values above pH 9, the harvest efficiency decreases, producing a whitish water with 10% (NH4)2SO4 solution. The oil profile (MO and S. obliquus) showed contents of SFA of 36.24–36.54%, monounsaturated fatty acids of 32.78–36.13%, and polyunsaturated fatty acids of 27.63–30.67%. The biodiesel obtained by S. obliquus and MO has poor cold flow properties, indicating possible applications limited to warm climates. For both biodiesels, good fuel ignition was observed according to the high cetane number and positive correlation with SFA and negative correlation with the degree of saturation. This supports the use of MO as a potentially harmless bioflocculant for microalgal harvest in wastewater, contributing to its treatment, and a possible source of low-cost biodiesel.